A Novel 3D Extended Network Cobalt Paradodecatungstate:Synthesis,Characterization and Crystal Structure of [Co（H2O）5]2[Co（H2O）4]3[H2W12O42]·11H2O

被引：0
|
作者：
WANG Jing-Pinga REN Qinga ZHAO Jun-Weib NIU Jing-Yanga② a (Institute of Molecular and Crystal Engineering
机构：
来源：
Chinese Journal of Structural Chemistry | 2006年 / 10期
基金：
中国国家自然科学基金;
关键词：
paradodecatungstate; polyoxometalate; cobalt; Keggin structure;
D O I：
10.14102/j.cnki.0254-5861.2006.10.002
中图分类号：
O614.812 [];
学科分类号：
070301 ; 081704 ;
摘要：
A cobalt paradodecatungstate [Co(H2O)5]2[Co(H2O)4]3[H2W12O42]·11H2O has been successfully synthesized and structurally characterized by X-ray crystallography. Structure analysis indicates that the title compound is of monoclinic, space group P21/n, with a = 13.449(3), b = 19.585(4), c = 13.990(3) , β = 113.79(3)°, V = 3371.8(12) ?3, Z = 2, R = 0.0519 and wR = 0.1242. The title compound exhibits a novel 3D extended network structure constructed by interconnecting the paradodecatungstate polyanion [H2W12O42]10- clusters and cobaltII coordination ions.
引用
收藏
页码：1167 / 1174
页数：8
相关论文
共 50 条
  • [11] Synthesis and crystal structure of [Co(H2O)6](C19H17O4SO3)2•8H2O
    Zhang, ZT
    Wang, QY
    STRUCTURAL CHEMISTRY, 2005, 16 (04) : 415 - 420
  • [12] Synthesis, structural characterization and properties of a 3D infinitely extended structural rare earth coordination compound of K3{[Sm(H2O)7]2Na[α-SiW11O39Sm(H2O)4]2} · 14 H2O· 14 H2O
    Jingping Wang
    Junwei Zhao
    Jingyang Niu
    Science in China Series B: Chemistry, 2005, 48 : 343 - 351
  • [13] Synthesis and Crystal Structure of CaCo(H2O)[BP2O8(OH)] • H2O
    Menezes, Prashanth W.
    Hoffmann, Stefan
    Prots, Yurii
    Kniep, Ruediger
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (4-5): : 614 - 617
  • [14] Synthesis, Crystal Structure and Antitumor Activities of a New Cobalt-containing Tungstoantimonate Na9[{Na(H2O)2}3{Co(H2O)}3(α-B-SbW9O33)2]•28H2O
    Tan, Rongxin
    Wang, Cheng
    Cui, Shuxin
    Wang, Hui
    Han, Junfeng
    Xie, Renguo
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2014, 51 (01): : 33 - 36
  • [15] Synthesis and Structure of a POMs-based 3D Zeolike Ionic Crystal, {[Co(dpdo)2(H2O)2(CH3CN)]2(SiMo12O40)(H2O)2}n
    Wei Mei-Lin
    Duan Chun-Ying
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (08) : 971 - 977
  • [16] Synthesis and Structure of a POMs-based 3D Zeolike Ionic Crystal,{[Co(dpdo)2(H2O)2(CH3CN)]2(SiMo12O40)(H2O)2}n
    魏梅林
    段春迎
    Chinese Journal of Structural Chemistry, 2009, 28 (08) : 971 - 977
  • [17] Hydrothermal Synthesis and Crystal Structure of [H4As8V14O42（H2O）]·6H2O
    CUI Xiao-Binga
    结构化学, 2004, (10) : 1138 - 1142
  • [18] Hydrothermal synthesis and crystal structure of [H4As8V14O42(H2O)]•6H2O
    Cui, XB
    Xu, JQ
    Li, GH
    Shi, Z
    Ding, H
    Yang, GY
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (10) : 1138 - 1142
  • [19] Syntheses, crystal structures and characterization of two zeotype crystals of K4[Cr3O(H2O)3(OOCH)6]2[P2W18O62] • 9.5H2O and K4[Cr3O(H2O)3(OOCH)6] • [H3P2W17Co(H2O)O61] • 20H2O
    Zhang Xin
    You Wan-sheng
    Zhu Zai-ming
    Dang Li-qin
    Sun Zhen-gang
    Zheng Xue-fang
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2007, 23 (01) : 8 - 13
  • [20] Syntheses and characterization of Co(pydc)(H2O)2 and Ni(pydc)(H2O) (pydc=3,5-pyridinedicarboxylate)
    Whitfield, T
    Zheng, LM
    Wang, XQ
    Jacobson, AJ
    SOLID STATE SCIENCES, 2001, 3 (08) : 829 - 835
12345