Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands

被引：1

作者：

LI Wen-Bin ^{[1
]}

GAO Zhu-Qing ^{[1
]}

GU Jin-Zhong ^{[2
]}

机构：

[1] School of Chemical and Biological Engineering,Taiyuan University of Science and Technology

[2] College of Chemistry and Chemical Engineering,Lanzhou University

来源：

结构化学 | 2016年 / 35卷 / 02期

关键词：

metal-organic framework; carboxylate ligand; magnetic properties;

D O I：

10.14102/j.cnki.0254-5861.2011-0929

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

摘要：

One new mixed-ligand coordination polymer,namely[Co;（btc）(bpdc);（py）;];（1）,was hydrothermally synthesized using biphenyl-2,4,4’-tricarboxylic acid（H;btc） as a main building block,along with two auxiliary ligands（H;bpdc = 2,2’-bipyridine-5,5’-dicarboxylic acid and py =pyridine）.The product 1 was characterized by IR spectroscopy,elemental,thermogravimetric,and single-crystal X-ray diffraction analyses.Single-crystal X-ray diffraction studies show that compound 1 possesses an intricate 3D metal-organic framework based on tetracobalt（Ⅱ） units.Magnetic susceptibility measurement indicates that compound 1 shows an antiferromagnetic coupling between the Co（Ⅱ） ions.

引用

页码：257 / 263

页数：7

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