Anodic oxidation is a prevalent technique to introduce superior corrosion and wear resistance upon the surface of titanium(Ti) alloys, in which the selection of appropriate electrolytes and defect-sealing strategies is a key. This study aims to address such issues through anodizing Ti-10V-2Fe-3Al alloy in malic acid, followed by a post-sealing treatment with Mg-Al layered double hydroxides(LDHs). The characteristics of the samples were investigated using scanning electron microscopy(SEM), atomic force microscopy(AFM), glow discharge optical emission spectroscopy(GDOES), X-ray diffraction(XRD) and energy-dispersive X-ray spectroscopy(EDS). SEM micrographs reveals that the anodic coating had a surface full of bulges and cracks, and was almost sealed by the following LDHs treatment. XRD pattern indicate that the anodic coating was mainly consisted of amorphous TiO;with a small fraction of anatase,but its crystallization degree was increased through the post-sealing. Moreover, electrochemical and tribological measurements demonstrate that corrosion current density was 2.8 × 10;, 2.0×10;, 5.9×10;A cm;, and wear rate was 1.45×10;, 1.30×10;and 6.90×10;mm;N;m;for respective bare Ti-10V-2Fe-3Al alloy substrate, anodized specimens without and with the LDHs post treatment. Finally, a plausible wear mechanism was proposed.