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CIDNP study of the photochemistry of 1-acetylindole-2,3-dione
被引：0
作者：
GUO Hongling YAN Baozhen WANG Xinyan WANG Ting School of Science Beijing University of Chemical Technology Beijing China Correspondence should be addressed to Guo Hongling email guohonglingcom
[100029
,1234
,163
]
机构：
关键词：
acetylindole-2;
3-dione;
CIDNP;
electron transfer;
hydrogen abstraction;
photochemistry;
D O I：
暂无
中图分类号：
O621.2 [有机化合物性质];
学科分类号：
070303 ;
081704 ;
摘要：
Chemically Induced Dynamic Nuclear Polarization (CIDNP) technique is applied to study the photochemical reactions of 1-acetylindole-2,3-dione (AID) with several hydrogen do- nors (1—13). These reactions take place by direct hydrogen abstraction of triplet excited AID from the corresponding 1—13 to give neutral radical pair intermediates, which afford polarized starting materials by back hydrogen transfer and give polarized coupling products by radical pair recombination.
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页码：115 / 121
页数：7
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