Influence of CeO2-ZrO2 and α-Al2O3 on Methane Partial Oxidation over Ni Catalyst

被引:0
|
作者
费亚南 [1 ]
沈美庆 [1 ]
石芳丽 [1 ]
王军 [1 ]
翁端 [2 ]
机构
[1] Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University  2. Department of Materials Science and Engineering, Tsinghua
关键词
Ni; CeO2-ZrO2; α-Al2O3; methane; partial oxidation; carbon deposition; rare earths;
D O I
暂无
中图分类号
O643.32 [催化反应];
学科分类号
081705 ;
摘要
The catalytic performance of Ni catalysts supported by CeO2-ZrO2 and α-Al2O3 was investigated for methane partial oxidation. Catalysts were measured by XRD. Carbon deposition was analyzed with TG-DTA and Raman. The results show that the activity and stability of catalysts supported on CeO2-ZrO2 are better than those on α-Al2O3. Combined with the characterizations results, the advantage of Ni/CeO2-ZrO2 in catalytic activity can be interpreted by fine Ni dispersion. TG-DTA results illustrate that Ni/CeO2-ZrO2 catalysts exhibit better coking resistance than α-Al2O3 supported catalyst.
引用
收藏
页码:100 / 103
页数:4
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