Palladium-catalyzed regioselective cascade reaction of carbon dioxide,amines and allenes for the synthesis of functionalized carbamates

被引:0
|
作者
Wenfang Xiong [1 ]
Ruixiang Cheng [1 ]
Bowen Wu [2 ]
Wanqing Wu [1 ,2 ]
Chaorong Qi [1 ,2 ]
Huanfeng Jiang [1 ]
机构
[1] Key Lab of Functional Molecular Engineering of Guangdong Province,School of Chemistry and Chemical Engineering,South China University of Technology
[2] State Key Lab of Luminescent Materials and Devices,South China University of Technology
基金
中国国家自然科学基金; 中国博士后科学基金; 中央高校基本科研业务费专项资金资助;
关键词
palladium; carbon dioxide; three-component reaction; carbamates; allenes;
D O I
暂无
中图分类号
TQ225.24 [];
学科分类号
0817 ;
摘要
A palladium-catalyzed regioselective three-component cascade reaction of carbon dioxide,amines and allenes has been developed,providing an expedient and practical method for the construction of a range of functionalized carbamates containing dihydrobenzofuran or indole moiety in moderate to excellent yields.The broad substrate scope,good functional group tolerance and excellent chemo-and regioselectivity are the features of the transformation.
引用
收藏
页码:331 / 335
页数:5
相关论文
共 50 条
  • [1] Palladium-catalyzed regioselective cascade reaction of carbon dioxide, amines and allenes for the synthesis of functionalized carbamates
    Wenfang Xiong
    Ruixiang Cheng
    Bowen Wu
    Wanqing Wu
    Chaorong Qi
    Huanfeng Jiang
    Science China Chemistry, 2020, 63 : 331 - 335
  • [2] Palladium-catalyzed regioselective cascade reaction of carbon dioxide, amines and allenes for the synthesis of functionalized carbamates
    Xiong, Wenfang
    Cheng, Ruixiang
    Wu, Bowen
    Wu, Wanqing
    Qi, Chaorong
    Jiang, Huanfeng
    SCIENCE CHINA-CHEMISTRY, 2020, 63 (03) : 331 - 335
  • [3] Palladium-catalyzed regioselective cascade reaction of carbon dioxide,amines and allenes for the synthesis of functionalized carbamates
    Wenfang Xiong
    Ruixiang Cheng
    Bowen Wu
    Wanqing Wu
    Chaorong Qi
    Huanfeng Jiang
    Science China(Chemistry), 2020, (03) : 331 - 335
  • [4] PALLADIUM-CATALYZED REGIOSELECTIVE AND STEREOSELECTIVE SYNTHESIS OF ALLYLIC AMINES
    TAMARU, Y
    BANDO, T
    KAWAMURA, Y
    OKAMURA, K
    YOSHIDA, Z
    SHIRO, M
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (20) : 1498 - 1500
  • [5] A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes
    Fu, Wai Chung
    Kwong, Fuk Yee
    CHEMICAL SCIENCE, 2020, 11 (05) : 1411 - 1417
  • [6] SYNTHESIS OF ALLYLIC AMINES THROUGH THE PALLADIUM-CATALYZED HYDROAMINATION OF ALLENES
    BESSON, L
    GORE, J
    GAZES, B
    TETRAHEDRON LETTERS, 1995, 36 (22) : 3857 - 3860
  • [7] Palladium-catalyzed selenoacylation of allenes leading to the regioselective formation of functionalized allyl selenides
    Toyofuku, Masashi
    Murase, Erika
    Fujiwara, Shin-ichi
    Shin-ike, Tsutomu
    Kuniyasu, Hitoshi
    Kambe, Nobuaki
    ORGANIC LETTERS, 2008, 10 (18) : 3957 - 3960
  • [8] Highly regioselective palladium-catalyzed thiocarbonylation of allenes with thiols and carbon monoxide
    Xiao, WJ
    Vasapollo, G
    Alper, H
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (08): : 2609 - 2612
  • [9] Highly Regioselective Palladium-Catalyzed Thiocarbonylation of Allenes with Thiols and Carbon Monoxide
    Xiao, W.-J.
    Vasapollo, G.
    Alper, H.
    Journal of Organic Chemistry, 63 (08):
  • [10] PALLADIUM-CATALYZED SYNTHESIS OF ALLENES
    JEFFERYLUONG, T
    LINSTRUMELLE, G
    TETRAHEDRON LETTERS, 1980, 21 (52) : 5019 - 5020