Highly ordered arrangement of meso-tetrakis(4-aminophenyl)porphyrin in self-assembled nanoaggregates via hydrogen bonding

被引：0

作者：

QingYun Liu ^{[1
,2
]}

QingYan Jia ^{[2
]}

JiQin Zhu ^{[2
]}

Qian Shao ^{[2
]}

JunFeng Fan ^{[2
]}

DongMei Wang ^{[2
]}

YanSheng Yin ^{[1
,3
]}

机构：

[1] College of Chemistry and Chemical Engineering,Ocean University of China

[2] College of Chemical and Environmental Engineering,Shandong University of Science and Technology

[3] Institute of Marine Materials Science and Engineering,Shanghai Maritime University

来源：

ChineseChemicalLetters | 2014年 / 25卷 / 05期

关键词：

Porphyrin; Self-assembly; Nanoaggregates; Highly ordered; Hydrogen bonding;

D O I：

暂无

中图分类号：

O641.3 [分子间的相互作用、超分子化学];

学科分类号：

070304 ; 081704 ;

摘要：

meso-Tetrakis(4-aminophenyl)porphyrin(TAPP) can self-assemble into nanostructures with different morphologies by a phase-transfer method.The morphologies(nanospheres,nanorods and nanothorns)of porphyrin nanoaggregates could be easily tuned just by changing the concentration of porphyrin in a proper solvent at room temperature.HRTEM images revealed the formation of highly ordered supramolecular arrays of TAPP,i.e. superlattice of TAPP molecules in nanoaggregates,which agreed well with the size of one molecule of TAPP.UV–vis absorption spectra showed an obvious red shift of the Soret band of TAPP,indicating the formation of J-aggregates of TAPP in nanoaggregates.

引用

页码：752 / 756

页数：5

共 2 条

[1] Synthesis,properties,and self-assembly of 2,3-bis(n-octyl)hexaazatriphenylene [J].

Zhi-Gang Tao ;

Tian-Guang Zhan ;

Tian-You Zhou ;

Xin Zhao ;

Zhan-Ting Li .

ChineseChemicalLetters, 2013, 24 (06) :453-456

[2] Ordered Nanosphere Alignment of Porphyrin for the Improvement of Nonlinear Optical Properties [J].

Huang, Changshui ;

Li, Yuliang ;

Song, Yinglin ;

Li, Yongjun ;

Liu, Huibiao ;

Zhu, Daoben .

ADVANCED MATERIALS, 2010, 22 (32) :3532-+

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