Hydrothermal Synthesis, Crystal Structure and Magnetic Property of a Novel Mixed Valence Decatungstate: [Cu（2,2′-bipy）2]2Na2W6VW4VIO30·2H2O

被引：0
|
作者：
李涛海
吕健
高水英
曹荣
机构：
[1] State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences
[2] Fuzhou Fujian 350002 China Graduate School of the Chinese Academy of Sciences Beijing 100039 China
[3] State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences
来源：
Chinese Journal of Structural Chemistry | 2008年 / 01期
关键词：
crystal structure; decatungstate; mixed valence; magnetic property;
D O I：
10.14102/j.cnki.0254-5861.2008.01.014
中图分类号：
O621.2 [有机化合物性质];
学科分类号：
070303 ; 081704 ;
摘要：
A novel Cu(II)-2,2′-bipy-supported (bipy = bipyridine) mixed valence decatungstate, [Cu(2,2′-bipy)2]2Na2W6VW4VIO30·2H2O 1, has been synthesized and structurally characterized by X-ray analysis. The crystal of 1 is of triclinic, space group P1 with a = 10.9393(10), b = 12.0492(2), c = 12.3783(2) , α = 80.631(10), β = 70.226(10), γ = 72.329(9)°, V = 1459.64(4) 3, Z = 1, Dc = 3.582 g/cm3, F(000) = 1404, R = 0.0553 and wR = 0.1242 for 4607 observed reflections (I > 2σ(I)). The EPR spectrum of 1 indicates that its unpaired electrons are placed in the dx2-y2 orbital of the ground state of CuII. Furthermore, compound 1 shows an antiferromagnetic interaction.
引用
收藏
页码：57 / 62
页数：6
相关论文
共 50 条
  • [21] Synthesis, crystal structure and luminescence property of [Co(hmz)2(H2O)4]•2H2O
    Zhang Shu-Guang
    Feng Yun-Long
    Wen Yi-Hang
    Hong, Su
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (06) : 664 - 668
  • [22] Hydrothermal synthesis and crystal structure of iron molybdophosphate Fe[Mo6O12(OH)3(H2PO4)(HPO4)2(PO4)]2-[Fe(2,2′-bipy)(H2O)2]2[Fe(2,2′-bipy)3]2•6H2O
    Guo, HX
    Liu, SX
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (10) : 1117 - 1122
  • [23] Synthesis and Crystal Structure of [{Mn(IBG)(2,2'-bipy)(H2O)}·4H2O]n
    徐涵
    李一志
    结构化学, 2010, 29 (03) : 483 - 487
  • [24] Synthesis and Crystal Structure of [{Mn(IBG)(2,2′-bipy)(H2O)}•4H2O]n
    Xu Han
    Li Yi-Zhi
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (03) : 483 - 487
  • [25] Hydrothermal Synthesis and Crystal Structure of Iron Molybdophosphate Fe[Mo6O12（OH）3（H2PO4）(HPO4)2（PO4）]2- [Fe（2,2′-bipy）(H2O)2]2[Fe（2,2′-bipy）3]2·6H2O
    GUO Hong-Xua
    结构化学, 2005, (10) : 1117 - 1122
  • [26] Crystal Structure and Magnetic and Fluorescent Properties of a New Copper(Ⅱ) Complex Cu2(L)4(2,2'-bipy)2(H2O)2
    YANG Ying-Qun
    ZHANG Shao-Hua
    TANG Si-Ping
    LI Wei
    结构化学, 2013, 32 (12) : 1841 - 1844
  • [27] Hydrothermal synthesis and structure of a mixed-valence polyoxotungstate decorated by copper(I) coordination group, [Cu(en)2H2O]2[{Cu(en)2}HPW12O40]•2H2O
    Li, Z
    Lin, BZ
    Han, GH
    Geng, F
    Liu, PD
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (05) : 608 - 614
  • [28] An oxovanadium(IV) complex derived from L-histidine, [V2O2(L-his)2(2,2′-bipy)2] • [C2H6O2 • (2,2′-bipy)]:: Hydrothermal synthesis, crystal structure and magnetic properties
    Yue, Huijuan
    Zhang, Dong
    Chen, Yan
    Shi, Zhan
    Feng, Shouhua
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (09) : 959 - 961
  • [29] Hydrothermal Synthesis and Structure of a Mixed-valence Polyoxotungstate Decorated by Copper（I） Coordination Group, [Cu（en）2H2O]2[{Cu（en）2}HPW12O40]·2H2O
    李真
    林碧洲
    韩国华
    耿凤
    刘培德
    Chinese Journal of Structural Chemistry, 2005, (05) : 608 - 614
  • [30] Hydrothermal synthesis and crystal structure of an inclusion compound [Mn(2,2′-bipy)(H2O)4]•(m-phth)
    Deng, YF
    Kuang, DZ
    Chen, MS
    Feng, YL
    Kuang, YF
    Peng, YL
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (03) : 551 - 554
12345