Geochemical Evaluation of the Permian Ecca Shale in Eastern Cape Province, South Africa:Implications for Shale Gas Potential

被引:0
作者
Christopher BAIYEGUNHI [1 ]
Kuiwu LIU [1 ]
Nicola WAGNER [2 ]
Oswald GWAVAVA [1 ]
Temitope LOLONINIYI [1 ]
机构
[1] Department of Geology, University of Fort Hare
[2] Department of Geology, University of Johannesburg
关键词
geochemistry; organic matter type; thermal maturity; hydrocarbons; Ecca Group; South Africa;
D O I
暂无
中图分类号
P618.13 [石油、天然气];
学科分类号
0709 ; 081803 ;
摘要
Shale gas has been the exploration focus for future energy supply in South Africa in recent time. Specifically, the Permian black shales of the Prince Albert, Whitehill, Collingham, Ripon and Fort Brown Formations are considered to be most prospective rocks for shale gas exploration. In this study,outcrop and core samples from the Ecca Group were analyzed to assess their total organic carbon(TOC), organic matter type, thermal maturity and hydrocarbon generation potential. These rocks have TOC ranging from 0.11 to 7.35 wt%. The genetic potential values vary from 0.09 to 0.53 mg HC/g,suggesting poor hydrocarbon generative potential. Most of the samples have Hydrogen Index(HI) values of less than 50 mg HC/g TOC, thus suggesting Type-Ⅳ kerogen. Tmax values range from 318℃ to601℃, perhaps indicating immature to over-maturity of the samples. The vitrinite reflectance values range from 2.22% to 3.93%, indicating over-maturity of samples. Binary plots of HI against Oxygen Index(OI), and HI versus Tmax show that the shales are of Type II and mixed Type Ⅱ-Ⅲ kerogen.Based on the geochemical data, the potential source rocks are inferred as immature to over-matured and having present-day potential to produce gas.
引用
收藏
页码:1193 / 1217
页数:25
相关论文
共 25 条
[1]  
Shale Gas Formation and Occurrence in China:An Overview of the Current Status and Future Potential[J]. ZOU Caineng,YANG Zhi,PAN Songqi,CHEN Yanyan,LIN Senhu,HUANG Jinliang,WU Songtao,DONG Dazhong,WANG Shufang,LIANG Feng,SUN Shasha,HUANG Yong,WENG Dingwei.Acta Geologica Sinica(English Edition). 2016(04)
[2]  
Petrographic, geochemical and petro-physical analysis of the Collingham Formation near Jansenville, Eastern Cape, South Africa – potential cap rocks to shale gas in the Karoo[J] . D.E. Black,P.W.K. Booth,M.J. de Wit.South African Journal of Geology . 2016 (1)
[3]  
U-PB zircon tuff geochronology from the Karoo Basin, South Africa: implications of zircon recycling on stratigraphic age controls[J] . Matthew P. McKay,Amy L. Weislogel,Andrea Fildani,Rufus L. Brunt,David M. Hodgson,Stephen S. Flint.International Geology Review . 2015 (4)
[4]  
The timing of the Cape Orogeny: New 40 Ar/ 39 Ar age constraints on deformation and cooling of the Cape Fold Belt, South Africa[J] . Jeroen Hansma,Eric Tohver,Christoph Schrank,Fred Jourdan,David Adams.Gondwana Research . 2015
[5]  
Shale Gas Characteristics of Permian Black Shales in South Africa: Results from Recent Drilling in the Ecca Group (Eastern Cape)[J] . Claire Geel,Hans-Martin Schulz,Peter Booth,Maarten deWit,Brian Horsfield.Energy Procedia . 2013
[6]  
High-precision temporal calibration of Late Permian vertebrate biostratigraphy: U-Pb zircon constraints from the Karoo Supergroup, South Africa[J] . Rubidge, B.S.,Erwin, D.H.,Ramezani, J.,Bowring, S.A.,de Klerk, W.J..Geology . 2013 (3)
[7]  
Paleozoic crustal blocks of onshore and offshore central Argentina: New pieces of the southwestern Gondwana collage and their role in the accretion of Patagonia and the evolution of Mesozoic south Atlantic sedimentary basins[J] . Francisco Pángaro,Víctor A. Ramos.Marine and Petroleum Geology . 2012 (1)
[8]  
Review and update of the applications of organic petrology: Part 1, geological applications[J] . International Journal of Coal Geology . 2012
[9]  
Metagenetic methane generation in gas shales I. Screening protocols using immature samples[J] . Nicolaj Mahlstedt,Brian Horsfield.Marine and Petroleum Geology . 2011 (1)
[10]  
Organic geochemical characteristics of the late Eocene–early Oligocene submarine fans and shelf deposits on Lemnos Island, NE Greece[J] . A. Maravelis,A. Zelilidis.Journal of Petroleum Science and Engineering . 2010 (3)