Facile synthesis and characterization of a novel thiophene-fused polycyclic aromatics based on pyrene

被引：0
作者：
Daiki Hoshino
Tsuyoshi Morita
Yasushiro Nishioka
机构：
[1] CollegeofScienceandTechnology,NihonUniversity,Narashinodai,Funabashi,Chiba,Japan
来源：
ChineseChemicalLetters | 2011年 / 22卷 / 07期
关键词：
Pyrene; Thiophene; Stille coupling reaction; Oxidative cyclization;
D O I：
暂无
中图分类号：
O621.3 [有机合成化学];
学科分类号：
070303 ; 081704 ;
摘要：
<正>A novel large thiophene-fused polycyclic aromatics 1 based on pyrene 5 has been synthesized,and its structure was confirmed by 1H NMR,13C NMR,MS,UV -vis and elemental analysis.The key steps of the synthesis involved the Stille cross-coupling reaction and followed by selectiveβ-βoxidative cyclization of pendant thienyl rings by FeCl3 under mild conditions.
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页码：819 / 822
页数：4
相关论文
共 14 条
[1]  
J.Luo,B.Zhao,H.S.O.Chan,et al. Journal of Materials Chemistry . 2010
[2]  
S.C.Lo,P.L.Burn. Chemical Reviews . 2007
[3]  
Y.Zhou,W.J.Liu,W.Zhang,et al. Journal of Organic Chemistry . 2006
[4]  
T.Yamato,A.Miyazawa,M.Tashiro. Chemische Berichte . 1993
[5]  
T.Yamato,M.Fujimoto,A.Miyazawa,et al. J.Chem.Soc,Perkin Trans.I . 1997
[6]  
Y.Didane,G.H.Mehl,A.Kumagai,et al. Journal of the American Chemical Society . 2008
[7]  
J.D.Tovar,A.Rose,T.M.Swager. Journal of the American Chemical Society . 2002
[8]  
W.J.Liu,Y.Zhou,Y Ma,et al. Organic Letters . 2007
[9]  
Y Zhou,W.J.Liu,Y.Ma,et al. Journal of the American Chemical Society . 2007
[10]  
P.Wilson,D.Lacey,S.Sharma,et al. Molecular Crystals and Liquid Crystals . 2001
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