Intermolecular and intramolecular electron transfer from eosin ester to viologen

被引：0
|
作者：
张丰雷
张曼华
沈涛
机构：
[1] Beijing 100101. China
[2] Institute of Photographic Chemistry. Chinese Academy of Sciences
来源：
Science in China,SerB | 1996年 / Ser.B1996卷 / 06期
基金：
中国国家自然科学基金;
关键词：
eosin-viologen linked compound; electron transfer; inclusion complex; rotaxane complex;
D O I：
暂无
中图分类号：
O631 [高分子物理和高分子物理化学];
学科分类号：
摘要：
The covalently -(CH2)10- linked eosin-butylviologen compound has been synthesized. The photoinduced electron transfer of eosin ester and butylviologen as well as the influence of addition of cyclodextrin or amylose into the solution of linked compound on the system have been studied by the absorption spectra, fluorescence spectra and fluorescence lifetime. The results indicated that the intramolecular electron transfer is much more efficient than the intermolecular one. Due to the formation of inclusion complex, the process of intramolecular electron transfer was changed after adding cydodextrin or amylose.
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页码：618 / 626
页数：9
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