Diamine anchored molecular junctions of oligo(phenylene ethynylene)cruciform

被引：0
|
作者：
Yuqing Liu [1 ,2 ,3 ,4 ]
Marco Santella [3 ]
Zhiqiang Fan [1 ]
Xintai Wang [3 ]
Xiangwei Jiang [1 ]
Mogens Br?ndsted Nielsen
Kasper N?rgaard
Bo W.Laursen [3 ]
Jingbo Li [1 ]
Zhongming Wei [1 ,2 ]
机构：
[1] State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences
[2] Sino-Danish College, University of Chinese Academy of Science
[3] Nano-Science Center and Department of Chemistry, University of Copenhagen
来源：
ChineseChemicalLetters | 2018年 / 29卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Oligo(phenylene-ethynylene); Tetrathiafulvalene; Diamine; Molecular electronics; Cruciform;
D O I：
暂无
中图分类号：
O621.1 [有机化学理论、物理有机化学];
学科分类号：
摘要：
Using diamine as anchoring group, the self-assembled monolayers(SAMs) based on oligo(phenyleneethynylene)s(OPEs) and cruciform OPEs with an extended tetrathiafulvalene(TTF)(OPE3 and OPE3-TTF)were successfully formed on the Au substrate. The Uniformity and stability of SAMs were confirmed through cyclic voltammetry(CV) and electrochemical reductive desorption. The investigation of transport properties of SAMs was achieved by conducting-probe atomic force microscopy(CP-AFM) with both Au and Pt tips. The results indicated that the conductance of OPE3-TTF was 17 and 46 times that of OPE3 for Au and Pt tips, respectively. Theoretical calculations are qualitatively consistent with the experimental results, suggesting that the diamine as anchoring group has a great potential in molecular electronics.
引用
收藏
页码：271 / 275
页数：5
相关论文
共 50 条
  • [1] Diamine anchored molecular junctions of oligo(phenylene ethynylene) cruciform
    Liu, Yuqing
    Santella, Marco
    Fan, Zhiqiang
    Wang, Xintai
    Jiang, Xiangwei
    Nielsen, Mogens Brondsted
    Norgaard, Kasper
    Laursen, Bo W.
    Li, Jingbo
    Wei, Zhongming
    CHINESE CHEMICAL LETTERS, 2018, 29 (02) : 271 - 275
  • [2] Molecular Junctions Based on SAMs of Cruciform Oligo(phenylene ethynylene)s
    Wei, Zhongming
    Li, Tao
    Jennum, Karsten
    Santella, Marco
    Bovet, Nicolas
    Hu, Wenping
    Nielsen, Mogens Brondsted
    Bjornholm, Thomas
    Solomon, Gemma C.
    Laursen, Bo W.
    Norgaard, Kasper
    LANGMUIR, 2012, 28 (08) : 4016 - 4023
  • [3] Structural versus Electrical Functionalization of Oligo(phenylene ethynylene) Diamine Molecular Junctions
    Teresa Gonzalez, M.
    Zhao, Xiaotao
    Manrique, David Zsolt
    Miguel, Delia
    Leary, Edmund
    Gulcur, Murat
    Batsanov, Andrei S.
    Rubio-Bollinger, Gabino
    Lambert, Colin J.
    Bryce, Martin R.
    Agrait, Nicolas
    JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (37): : 21655 - 21662
  • [4] Molecular Heterojunctions of Oligo(phenylene ethynylene)s with Linear to Cruciform Framework
    Wei, Zhongming
    Hansen, Tim
    Santella, Marco
    Wang, Xintai
    Parker, Christian R.
    Jiang, Xingbin
    Li, Tao
    Glyvradal, Magni
    Jennum, Karsten
    Glibstrup, Emil
    Bovet, Nicolas
    Wang, Xiaowei
    Hu, Wenping
    Solomon, Gemma C.
    Nielsen, Mogens Brondsted
    Qiu, Xiaohui
    Bjornholm, Thomas
    Norgaard, Kasper
    Laursen, Bo W.
    ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (11) : 1700 - 1708
  • [5] Asymmetric Effect on the Length Dependence of Oligo(Phenylene ethynylene)-Based Molecular Junctions
    Fan, Yinqi
    Pitie, Sylvain
    Liu, Chenguang
    Zhao, Cezhou
    Zhao, Chun
    Seydou, Mahamadou
    Dappe, Yannick J.
    Nichols, Richard J.
    Yang, Li
    JOURNAL OF PHYSICAL CHEMISTRY C, 2022, 126 (07): : 3635 - 3645
  • [6] Rectifying Properties of Oligo(Phenylene Ethynylene) Heterometallic Molecular Junctions: Molecular Length and Side Group Effects
    Xiao-Xiao Fu
    Rui-Qin Zhang
    Guang-Ping Zhang
    Zong-Liang Li
    Scientific Reports, 4
  • [7] Rectifying Properties of Oligo(Phenylene Ethynylene) Heterometallic Molecular Junctions: Molecular Length and Side Group Effects
    Fu, Xiao-Xiao
    Zhang, Rui-Qin
    Zhang, Guang-Ping
    Li, Zong-Liang
    SCIENTIFIC REPORTS, 2014, 4
  • [8] A review of oligo(arylene ethynylene) derivatives in molecular junctions
    O'Driscoll, Luke J.
    Bryce, Martin R.
    NANOSCALE, 2021, 13 (24) : 10668 - 10711
  • [9] Temperature dependence of charge transport in solid-state molecular junctions based on oligo(phenylene ethynylene)s
    Liu, Yuqing
    Zhong, Mianzeng
    Downey, Elisabeth Ffion
    Chen, Xiaoyao
    Li, Tao
    Norgaard, Kasper
    Wei, Zhongming
    NANOTECHNOLOGY, 2020, 31 (16)
  • [10] Molecular packing and morphology of oligo(m-phenylene ethynylene) foldamers
    Kübel, C
    Mio, MJ
    Moore, JS
    Martin, DC
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (29) : 8605 - 8610
12345