Crystal Structure of catena-[(Tetrakis-μ2-acetato-μ2-4,4'-bipyridine) dicopper(Ⅱ)] Acetonitrile Solvate

被引：0

作者：

温一航 ^{[1
]}

何银华 ^{[1
]}

冯云龙 ^{[1
]}

NG Seik Weng ^{[2
]}

机构：

[1] Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University 2. Department of Chemistry, University of Malaya,Kuala Lumpur 50603, Mala

来源：

Chinese Journal of Structural Chemistry | 2007年 / 01期

关键词：

Cu complex; paddle-wheel unit; crystal structure; guest molecule;

D O I：

10.14102/j.cnki.0254-5861.2007.01.005

中图分类号：

O626 [杂环化合物];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound, [Cu2(CH3COO)4(C8H10N2)]n·nCH3CN 1 (C8H10N2, 4,4-bipy = 4,4-bipyridine), has been solvothermally synthesized in CH3CN and characterized by X-ray diffraction. The crystal is of monoclinic, space group Cc with a = 22.626(6), b = 14.012(4), c = 15.106(4) ?, β = 107.610(3)o, V = 4565(2) 3, C20H23Cu2N3O8, Mr = 560.49, Z = 8, Dc = 1.631 g/cm3, μ = 1.914 mm-1, Flack parameter = 0.48(1), F(000) = 2288, R = 0.042 and wR = 0.098 for 8887 observed reflections (I > 2σ(I)). It consists of nearly linear one-dimensional chains [Cu2(CH3COO)4(C8H10N2)]n derived from paddle-wheel [Cu2(CH3COO)4] unit linked by 4,4?-bipy, and CH3CN as guest molecule regularly decorates between the chains.

引用

页码：29 / 32

页数：4