Composition optimization of high-strength Mg-Gd-Y-Zr alloys based on the structural unit of Mg-Gd solid solution

被引:13
作者
Rui Jiang [1 ]
Shengnan Qian [1 ]
Chuang Dong [1 ,2 ]
Ying Qin [1 ]
Yujuan Wu [3 ]
Jianxin Zou [3 ]
Xiaoqin Zeng [3 ]
机构
[1] Key Laboratory of Materials Modification (Ministry of Education), School of Material Science and Engineering, Dalian University of Technology
[2] School of Materials Science and Engineering, Dalian Jiaotong University
[3] National Engeering Research Center of Light Alloys Net Forming, School of Material Science and Engineering, Shanghai Jiao Tong University
关键词
Mg-Gd solid solution; Chemical unit; Cluster-plus-glue-atom unit; Mg-Gd-Y-Zr cast alloys;
D O I
暂无
中图分类号
TG146.22 [];
学科分类号
080502 ;
摘要
Mg-Gd-Y-Zr alloys with high strength fall within narrow composition range.The present paper explains their composition rule by establishing the cluster-plus-glue-atom unit of Gd-containing Mg solid solution with the aid of Mg matrix and Mg5Gd precipitate phase.First,based on the structural homologue between Gd-containing Mg solid solution and Mg5Gd precipitate phase and in combination with our previously established method for calculating the glue atoms,[Gd-Mg12]Mg5is obtained as the chemical unit of Gd-containing Mg solid solution.Then,seven compositions are designed using different combinations of this unit and that of pure Mg [Mg-Mg12Mg3.After a systematic experimental investigation on the microstructure and mechanical property evolutions as a function of the unit proportions,it is revealed that the Mg-10.1 Gd-3.3 Y-0.9 Zr alloy,being issued from equi-proportion mixing of the two units,shows the strongest tendency of precipitation and reaches the highest strength of 374 MPa after aging.The composition and strength of this alloy are quite close to GW103 K which is well recognized for its general mechanical performance in Mg-Gd-Y-Zr system.
引用
收藏
页码:104 / 113
页数:10
相关论文
共 15 条
  • [1] Thermodynamics and kinetics of phase transformation in rare earth–magnesium alloys: A critical review
    Qun Luo
    Yanlin Guo
    Bin Liu
    Yujun Feng
    Jieyu Zhang
    Qian Li
    Kuochih Chou
    [J]. Journal of Materials Science & Technology, 2020, 44 (09) : 171 - 190
  • [2] Tensile properties of high strength cast Mg alloys at room temperature:A review[J]. Fu Penghuai,Peng Liming,Jiang Haiyan,Ding Wenjiang,Zhai Chunquan.China Foundry. 2014(04)
  • [3] Dual-cluster interpretation of binary eutectics associated with hexagonal close-packed solid solution phases[J] . Shuang Zhang,Chuang Dong.Materials Letters . 2018
  • [4] 24 electron cluster formulas as the 'molecular' units of ideal metallic glasses
    Luo, L. J.
    Chen, H.
    Wang, Y. M.
    Qiang, J. B.
    Wang, Q.
    Dong, C.
    Haeussler, P.
    [J]. PHILOSOPHICAL MAGAZINE, 2014, 94 (22) : 2520 - 2540
  • [5] Effect of Gd content on microstructure and mechanical properties of Mg–Gd–Y–Zr alloys under peak-aged condition[J] . H.R. Jafari Nodooshan,Wencai Liu,Guohua Wu,You Rao,Chenxu Zhou,Shipeng He,Wenjiang Ding,R. Mahmudi.Materials Science & Engineering A . 2014
  • [6] On the unexpected formation of rare earth hydrides in magnesium–rare earth casting alloys[J] . Zhu S.M.,Nie J.F.,Gibson M.A.,Easton M.A..Scripta Materialia . 2014
  • [7] The e/a values of ideal metallic glasses in relation to cluster formulae
    Han, Guang
    Qiang, Jianbing
    Li, Fengwei
    Yuan, Liang
    Quan, Shiguan
    Wang, Qing
    Wang, Yingmin
    Dong, Chuang
    Haeussler, Peter
    [J]. ACTA MATERIALIA, 2011, 59 (15) : 5917 - 5923
  • [8] Effect of microalloying with rare-earth elements on the texture of extruded magnesium-based alloys
    Stanford, N.
    Atwell, D.
    Beer, A.
    Davies, C.
    Barnett, M. R.
    [J]. SCRIPTA MATERIALIA, 2008, 59 (07) : 772 - 775
  • [9] Microstructural characterisation of as cast and homogenised Mg–Gd–Nd–Zr alloys[J] . Zheng,Dong,Zeng,Ding.Materials Science and Technology . 2008 (3)
  • [10] Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element (Overview)[J] . Akira Takeuchi,Akihisa Inoue.Materials transactions . 2005 (12)