Are matrix isolated species really “isolated”? Infrared spectroscopic and theoretical studies of noble gas-transition metal oxide complexes

被引：0

作者：

ZHAO YanYing ZHOU MingFei Department of Chemistry Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials Advanced Materials Laboratory Fudan University Shanghai China ^{[200433
]}

机构：

来源：

Science China(Chemistry) | 2010年 / 53卷 / 02期

关键词：

noble gas complexes; transition metal oxides; matrix isolation; infrared spectroscopy;

D O I：

暂无

中图分类号：

O641.1 [化学键理论];

学科分类号：

070304 ; 081704 ;

摘要：

In this review, we summarize our recent results on matrix isolation infrared spectroscopic studies and theoretical investigations of noble gas-transition metal oxide complexes. The results show that some transition metal oxide species trapped in solid noble gas matrices are chemically coordinated by one or multiple noble gas atoms forming noble gas complexes and, hence, cannot be regarded as isolated species. Noble gas coordination alters the vibrational frequencies as well as the geometric and electronic structures of transition metal oxide species trapped in solid noble gas matrixes. The interactions between noble gas atoms and transition metal oxides involve ion-induced dipole interactions as well as chemical bonding interactions. Periodic trends in the bonding in these noble gas-transition metal complexes are discussed.

引用

页码：327 / 336

页数：10

共 12 条

[1]

Probing the intermediates in the MO + CH4 ? M + CH3OH reactions by matrix isolation infrared spectroscopy[J] . Guanjun Wang,Mingfei Zhou.International Reviews in Physical Chemistry . 2008 (1)

[2]

K[J] . Z. anorg. allg. Chem. . 2003 (7‐8)

[3] Similarities and differences in the structure of 3d-metal monocarbides and monoxides [J].

Gutsev, GL ;

Andrews, L ;

Bauschlicher, CW .

THEORETICAL CHEMISTRY ACCOUNTS, 2003, 109 (06) :298-308

[4]

Theoretical study of the first transition row oxides and sulfides[J] . Charles W. Bauschlicher,Phillippe Maitre.Theoretica Chimica Acta . 1995 (2)

[5]

Energy-adjusted ab initio pseudopotentials for the second and third row transition elements[J] . Theoretica Chimica Acta . 1990 (2)

[6]

Spectroscopy of the Diatomic 3d Transition Metal Oxides[J] . A J Merer.Annual Review of Physical Chemistry . 1989

[7]

AB Initio Studies of Transition Metal Systems[J] . S R Langhoff,C W Bauschlicher.Annual Review of Physical Chemistry . 1988

[8]

Insights into the xenon-silver halide interaction from a rotational spectroscopic study of XeAgF and XeAgCl .2 Cooke,S. A,Gerry,M. C. L. Phys. Chem. Chem. Phys . 2004

[9]

Noble Gas-Actinide Compounds, Complexation of the CUO Molecule by Ar, Kr, and Xe Atoms in Noble Gas Matrices .2 Li,J,Bursten,B. E,Liang,B,Andrews,L. Science . 2002

[10]

Gold(Ⅰ) and Mercury(Ⅱ) Xenon Complexes .2 Hwang,I -C,Seidel,S,Seppelt,K. Angew. Chem. Int. Ed . 2003

← 1 2 →