Expedient copper-catalyzed borylation reactions using amino acids as ligands

被引：0

作者：

Meng-Yan Liu ^{[1
,2
]}

Shi-Bin Hong ^{[1
,2
]}

Wei Zhang ^{[1
,2
]}

Wei Deng ^{[1
,2
]}

机构：

[1] Research Center of Nano Science and Technology,Shanghai University

[2] School of Chemical and Engineering,Shanghai Institute of Technology

来源：

ChineseChemicalLetters | 2015年 / 26卷 / 03期

基金：

上海市自然科学基金;

关键词：

Cu-catalyzed; Borylation; Amino acid; Alkylboronic; Organoboron;

D O I：

暂无

中图分类号：

O621.251 [];

学科分类号：

070303 ; 081704 ;

摘要：

Amino acids were found to be as good ligands for copper-catalyzed borylation reactions of primary and secondary alkyl halides,and the B2pin2 acted as bi-boron source for borylation.The high reaction efficiency and mild conditions make the new catalyst system a useful alternative to the recently developed methods for the preparation of alkylboronic esters.

引用

页码：373 / 376

页数：4

共 4 条

[1] Alkylboronic Esters from Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides
Yang, Chu-Ting
Zhang, Zhen-Qi
Tajuddin, Hazmi
Wu, Chen-Cheng
Liang, Jun
Liu, Jing-Hui
Fu, Yao
Czyzewska, Maria
Steel, Patrick G.
Marder, Todd B.
Liu, Lei
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[2] Copper-catalyzed cross-coupling of sulfonamides with aryl iodides and bromides facilitated by amino acid ligands
Deng, W
Liu, L
Zhang, C
Liu, M
Guo, QX
[J]. TETRAHEDRON LETTERS, 2005, 46 (43) : 7295 - 7298
[3] Amino acid-mediated Goldberg reactions between amides and aryl iodides
Deng, W
Wang, YF
Zou, W
Liu, L
Guo, QX
[J]. TETRAHEDRON LETTERS, 2004, 45 (11) : 2311 - 2315
[4] CuI-catalyzed coupling reactions of aryl iodides and bromides with thiols promoted by amino acid ligands
Deng, W
Zou, Y
Wang, YF
Liu, L
Guo, QX
[J]. SYNLETT, 2004, (07) : 1254 - 1258

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