Ce(SO4)2-mediated Oxidative Coupling of Primary Aromatic Amines in Water

被引：0
|
作者：
LU Wen-chao and XI Chan-juan Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology
机构：
来源：
Chemical Research in Chinese Universities | 2009年 / 25卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Primary aromatic amine; Oxidative coupling; Cerium sulfate;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
The oxidative coupling of primary aromatic amines was investigated. Ce(SO4)2 can mediate the oxidative coupling of primary aromatic amines in water to dimers, trimers and/or tetramers, which depended on the substituents of primary aromatic amines. When 2,6-dimethylaniline or 2,6-diethylaniline was used as substrate, dimer, and tetramer were formed as major products. When 2,6-diisopropylaniline or 2,6-dihaloanilines was used as substrate, dimer, and trimer were formed. The mechanistic aspect was also investigated.
引用
收藏
页码：638 / 643
页数：6
相关论文
共 50 条
  • [1] Ce(SO4)2-mediated Oxidative Coupling of Primary Aromatic Amines in Water
    Lu Wen-chao
    Xi Chan-juan
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2009, 25 (05) : 638 - 643
  • [2] Ce(SO4)2-mediated nitration of N,N-dialkylanilines with NaNO2 in water
    Yang, Xianghua
    Xi, Chanjuan
    SYNTHETIC COMMUNICATIONS, 2007, 37 (19-21) : 3381 - 3392
  • [3] STRUCTURE OF CE(SO4)2
    ROGACHEV, DL
    PORAIKOSHITS, MA
    KUZNETSOV, V
    DIKAREVA, LM
    JOURNAL OF STRUCTURAL CHEMISTRY, 1974, 15 (03) : 397 - 401
  • [4] Liquid chromatography analysis of the phenol and Ce(SO4)2 mediated electrooxidation products
    Goncea, CM
    Oniciu, L
    Marutoiu, C
    Filip, M
    REVISTA DE CHIMIE, 1999, 50 (03): : 216 - 220
  • [5] DETERMINATION OF MIXING OF 4F-LIGAND ORBITALS IN CE(SO4)2 BY XANES IS CE(SO4)2 A MIXED VALENT INSULATING SYSTEM
    BIANCONI, A
    MARCELLI, A
    TOMELLINI, M
    DAVOLI, I
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1985, 47-8 (FEB) : 209 - 211
  • [6] Ce(SO4)2•4H2O Mediated Synthesis of Flavones and 2-Phenyl-4-quinolones
    Liu, Ruihuan
    Wang, Xuli
    Cheng, Fei
    Li, Fushuang
    Xu, Kangping
    Tan, Guishan
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2016, 36 (11) : 2677 - 2682
  • [7] PHASE DIAGRAM OF LI2SO4-CE2(SO4)3 SYSTEM
    VOLK, VI
    ZAITSEVA, LL
    ZHURNAL NEORGANICHESKOI KHIMII, 1971, 16 (10): : 2845 - &
  • [8] Saccharinato complexes of Ce(V) with 2-hydroxypyridine:: Synthesis, spectroscopic and thermal characteristics of [Ce(sac)2(SO4)(H2O)4] and [Ce(sac)2(SO4)(PyOH)2]
    Gaballa, Akmal S.
    Teleb, Said M.
    Mueller, Thomas
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2008, 70 (05) : 1187 - 1192
  • [9] Synthesis of Unsymmetrical Aromatic Azoxy Compounds by Silver-Mediated Oxidative Coupling of Aromatic Amines with Nitrosoarenes
    Ding, Weijie
    Xu, Shengshi
    Yu, Xiaochun
    Wang, Shun
    ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (06) : 1394 - 1399
  • [10] Oxidative Coupling of Aromatic Amines and Nitrosoarenes: Iodine-Mediated Formation of Unsymmetrical Aromatic Azoxy Compounds
    Yu, Xiaochun
    Ding, Weijie
    Ge, Panyu
    Wang, Shun
    Wang, Jichang
    ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (16) : 3150 - 3156
12345