Synthesis, Crystal Structure and Properties of a New One-Dimensional 3d-4f Compound

被引：0

作者：

赵琦华

王庆华

方瑞斌

陈志达

机构：

[1] Department of Chemistry

[2] Yunnan University

[3] Kunming

[4] Yunnan 650091

[5] China

[6] School of Pharmacy

[7] China

[8] State Key Laboratory of Rare Materials Chemistry and Applications

[9] College of Chemistry and Molecular Engineering

[10] Peking University

[11] Beijing 100871

来源：

Chinese Journal of Chemistry | 2004年 / 03期

关键词：

d-4f heterometallic; cyano-bridged complex; crystal structure; magnetic property;

D O I：

暂无

中图分类号：

O627 [元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

A new heterometallic complex K2[{Eu(H2O)4}2{FeII(bipy)(CN)4}4]·9H2O·CH3OH [bipy=2,2’-bipyridine] was synthesized. The compound has been characterized by X-ray structure analysis, elemental analyses, IR spectrum, TGA thermogram and magnetic susceptibility. The complex consists of novel one-dimensional ladder structure. The crystal belongs to monoclinic system with a space group P21/c, a =1.3946(4) nm, b=2.0450(6) nm, c=2.9722(8) nm, b=99.025(5), V=8.372(4) nm3, Z=4, Dc=1.562 g·cm-3.

引用

页码：264 / 267 +221

页数：5