A New Copper Coordination Polymer with Magnetic Property Based on 3-(1,2,4-Triazol-1-yl)benzoic Acid

被引：1

作者：

张亨达 ^{[1
,2
]}

王帅华 ^{[1
]}

吴少凡 ^{[1
]}

机构：

[1] Key Laboratory of Optoelectronic Materials Chemistry and Physics,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

[2] University of Chinese Academy of Sciences

来源：

结构化学 | 2017年 / 36卷 / 11期

关键词：

copper coordination polymer; hydrothermal reaction; crystal structure; magnetic property;

D O I：

10.14102/j.cnki.0254-5861.2011-1615

中图分类号：

O631 [高分子物理和高分子物理化学]; O641.4 [络合物化学（配位化学）];

学科分类号：

070305 ; 080501 ; 081704 ; 070304 ;

摘要：

A copper coordination polymer, namely [CuL2（H2O）2]·H2O 1(HL = 3-（1,2,4-triazol-1-yl）benzoic acid) has been synthesized by the hydrothermal reaction under 140 oC. The structure of 1 was characterized by single-crystal X-ray diffraction analysis, elemental analyses, powder X-ray diffraction, IR spectroscopy, and thermogravimetric analysis. Single-crystal X-ray diffraction analysis reveals that 1 crystallizes in P21/n space group with a = 12.374（5）, b = 12.730（5）, c = 12.561（5） ?, β = 91.105（9）o, V = 1978.2（14） ?3, Z = 4, Dc = 1.618 g/cm3, μ = 1.160 mm-1, F（000） = 964, the final R = 0.0449 and w R = 0.1443 with I > 2σ（I）. Magnetic measurements show that 1 exhibits antiferromagnetic interactions by the analysis of magnetic test data.

引用

页码：1912 / 1917

页数：6

共 3 条

[1]

Second-order nonlinear optics in coordination chemistry: An open door towards multi-functional materials and molecular switches[J] . Pascal G. Lacroix,Isabelle Malfant,Christine Lepetit.Coordination Chemistry Reviews . 2015

[2]

Crystal structure refinement with SHELXL[J] . George M. Sheldrick.Acta Crystallogr C Struct Chem . 2015 (Pt 1)

[3]

A short history of SHELX[J] . George M.Sheldrick.Acta Cryst. A . 2008 (1)

← 1 →