Interfacial Synthesis of δ-MnO2 Nano-sheets with a Large Surface Area and Their Application in Electrochemical Capacitors

被引:0
作者
Zhijun Jia [1 ]
Jun Wang [1 ]
Yi Wang [1 ,2 ]
Bingyang Li [3 ]
Baoguo Wang [3 ]
Tao Qi [1 ]
Xin Wang [2 ]
机构
[1] National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences
[2] Department of Chemical Engineering, Tsinghua University
[3] School of Chemical and Biomedical Engineering, Nanyang Technological University
基金
中国国家自然科学基金;
关键词
Oxides; Nanostructures; Chemical synthesis; Electron microscopy; Electrochemical properties;
D O I
暂无
中图分类号
TB383.1 []; TM53 [电容器];
学科分类号
070205 ; 080501 ; 080801 ; 1406 ;
摘要
Birnessite-type MnO(δ-MnO) nano-sheets were successfully synthesized by an interfacial synthesis method in this work.The properties and electrochemical performance of the as-prepared δ-MnOwere analyzed and evaluated by scanning electron microscopy(SEM),X-ray diffraction(XRD),nitrogen adsorption measurement and electrochemical tests.This facile synthesis method enables δ-MnOnanosheets to show a large specific surface area(257.5 m~2 g).The electrochemical test results show that the specific capacitance is 272 Fgand the specific capacitance retention is over 96.7%after 1000 cycles at a scan rate of 10 mV s.All results demonstrate that δ-MnOhas a great potential application in highperformance electrochemical capacitors,and this interfacial synthesis method will be a very promising method to synthesize highly active MnOmaterials in a large scale.
引用
收藏
页码:147 / 152
页数:6
相关论文
共 10 条
[1]  
Synthesis and enhanced electrochemical supercapacitive properties of manganese oxide nanoflake electrodes[J] . A.I. Inamdar,Y. Jo,J. Kim,J. Han,S.M. Pawar,R.S. Kalubarme,C.J. Park,J.P. Hong,Y.S. Park,W. Jung,H. Kim,Hyunsik Im.Energy . 2015
[2]  
Layered manganese oxides-decorated and nickel foam-supported carbon nanotubes as advanced binder-free supercapacitor electrodes[J] . Ming Huang,Rui Mi,Hao Liu,Fei Li,Xiao Li Zhao,Wei Zhang,Shi Xuan He,Yu Xin Zhang.Journal of Power Sources . 2014
[3]  
Controllable syntheses of α- and δ-MnO 2 as cathode catalysts for zinc-air battery[J] . Youju Huang,Yuli Lin,Weishan Li.Electrochimica Acta . 2013
[4]  
Interfacial synthesis of mesoporous MnO 2 /polyaniline hollow spheres and their application in electrochemical capacitors[J] . Jian-Gan Wang,Ying Yang,Zheng-Hong Huang,Feiyu Kang.Journal of Power Sources . 2012
[5]  
Microwave–hydrothermal synthesis of birnessite-type MnO 2 nanospheres as supercapacitor electrode materials[J] . Bangsheng Ming,Jianling Li,Feiyu Kang,Guoyao Pang,Yakun Zhang,Liang Chen,Junyuan Xu,Xindong Wang.Journal of Power Sources . 2011
[6]  
A study on charge storage mechanism of α-MnO 2 by occupying tunnels with metal cations (Ba 2+ , K + )[J] . Dengyun Zhai,Baohua Li,Chengjun Xu,Hongda Du,Yanbing He,Chunguang Wei,Feiyu Kang.Journal of Power Sources . 2011 (18)
[7]  
Charge storage mechanism of manganese dioxide for capacitor application: Effect of the mild electrolytes containing alkaline and alkaline-earth metal cations[J] . Chengjun Xu,Chunguang Wei,Baohua Li,Feiyu Kang,Zhicheng Guan.Journal of Power Sources . 2011 (18)
[8]   Low-temperature synthesis of δ-MnO2 with large surface area and its capacitance [J].
Zhu, Gang ;
Li, Hongjuan ;
Deng, Lingjuan ;
Liu, Zong-Huai .
MATERIALS LETTERS, 2010, 64 (16) :1763-1765
[9]   Interface synthesis of mesoporous MnO2 and its electrochemical capacitive behaviors [J].
Yuan, Changzhou ;
Gao, Bo ;
Su, Linghao ;
Zhang, Xiaogang .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 322 (02) :545-550
[10]   Electrochemical properties of nanosized hydrous manganese dioxide synthesized by a self-reacting microemulsion method [J].
Xu, Chengjun ;
Li, Baohua ;
Du, Hongda ;
Kang, Feiyu ;
Zeng, Yuqun .
JOURNAL OF POWER SOURCES, 2008, 180 (01) :664-670