LINEAR ENTHALPY RELATIONSHIPS BETWEEN HEATS OF FORMATION OF COMPLEX COMPOUNDS AND HEATS OF PRO TONATION OF LIGANDS——COPPER(Ⅱ)-N-(PARA-SUBSTITUTED PHENYL) GLYCINES

被引：0

作者：

陈荣悌

古宗信

林华宽

刘恒潜

机构：

[1] Tianjin

[2] Department of Chemistry

[3] Nankai University

来源：

Science in China,SerB. | 1985年 / Ser.B.1985卷 / 11期

关键词：

heat; PARA-SUBSTITUTED PHENYL; COPPER; GLYCINES; LINEAR ENTHALPY RELATIONSHIPS BETWEEN HEATS OF FORMATION OF COMPLEX COMPOUNDS AND HEATS OF PRO TONATION OF LIGANDS;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The heats of protonation of N-（para-substituted phenyl） glycines （R—CH—NHCHCOOH, R=CHO, CH, H, C1） and the heats of formation of these amino acids with copper（Ⅱ） have been determined calorimetrically at 25℃ in 30% （v/v） ethanol in the presence of 0.1M sodium perchlorate. The data obtained conform nicely to the equation △H-Q-β△Hwhere △Hdenotes the heats of formation of complex compounds, △Hdenotes the heats of protonation of the ligands, and Q and β are constants.

引用

页码：1151 / 1156

页数：6

共 18 条

[1] LINEAR ENTHALPY RELATIONSHIPS BETWEEN HEATS OF FORMATION OF COMPLEX-COMPOUNDS AND HEATS OF PROTONATION OF LIGANDS - COPPER(II)-N-(PARA-SUBSTITUTED PHENYL) GLYCINES
CHEN, RT
GU, ZX
LIN, HK
LIU, HQ
SCIENTIA SINICA SERIES B-CHEMICAL BIOLOGICAL AGRICULTURAL MEDICAL & EARTH SCIENCES, 1985, 28 (11) : 1151 - 1156
[2] LINEAR ENTHALPY RELATIONSHIPS BETWEEN HEATS OF FORMATION OF COMPLEX-COMPOUNDS AND HEATS OF PROTONATION OF LIGANDS - COPPER(II) N-(PARA-SUBSTITUTED PHENYL)IMINODIACETIC ACID ALPHA-AMINO-ACIDS TERNARY-SYSTEM AND COPPER(II) N-(PARA-SUBSTITUTED PHENYL)IMINOACETIC ACIDS BINARY-SYSTEM
LIN, HK
LIU, SX
GU, ZX
CHEN, YT
INORGANICA CHIMICA ACTA, 1990, 175 (01) : 91 - 98
[3] LINEAR ENTHALPY RELATIONSHIPS BETWEEN HEATS OF FORMATION OF COMPLEX COMPOUNDS AND HEATS OF LIGANDS III. COPPER(II)-2,2 '-BIPYRIDYL-COPPER(II)-PHENANTHROLINE-N- (meta-SUBSTITUTED PHENYL) GLYCINES TERNARY SYSTEMS
Chen, Y. T.
Lin Huakuan
Gu Zongxin
ACTA PHYSICO-CHIMICA SINICA, 1986, 2 (05) : 452 - 456
[4] LINEAR RELATIONSHIPS BETWEEN THE HEATS OF FORMATION OF COMPLEX COMPOUNDS AND THE HEATS OF PROTONATION OF LIGANDS VII Ni(II)-N,N '-BIS (para-SUBSTITUTED PHENYL) ETHYLENEDIAMINE BINARY AND Ni(II)-BIPY-TERNARY SYSTE
Lin Huakuan
Zhu Junying
Gu Zongxin
Chen Rongti
ACTA PHYSICO-CHIMICA SINICA, 1989, 5 (05) : 531 - 535
[5] LINEAR ENTHALPY RELATIONSHIPS BETWEEN THE HEATS OF FORMATION OF COORDINATION-COMPOUNDS AND THE HEATS OF PROTONATION OF THE LIGANDS - THE COPPER(II) N-(META-SUBSTITUTED PHENYL)-IMINODIACETIC ACID ALPHA-AMINO-ACID COMPETITIVE TERNARY-SYSTEM
LIN, HK
LIU, SX
GU, ZX
CHEN, YT
THERMOCHIMICA ACTA, 1990, 164 : 353 - 363
[6] LINEAR FREE-ENERGY RELATIONSHIPS BETWEEN REACTION-RATE CONSTANTS AND EQUILIBRIUM-CONSTANTS OF COMPLEX-COMPOUNDS .2. BINARY COMPLEX-FORMATION KINETICS OF N-(PARA-SUBSTITUTED PHENYL)GLYCINES WITH NICKEL(II)
CHEN, RT
CHEN, YT
ZHANG, QY
LI, YJ
ACTA CHIMICA SINICA, 1988, 46 (08) : 751 - 756
[7] LINEAR FREE-ENERGY RELATIONSHIPS BETWEEN STABILITY OF COMPLEX-COMPOUNDS AND STRENGTHS OF ACID AND BASE OF LIGANDS .5. THE STABILITY OF COMPLEX-COMPOUNDS FORMED FROM 1, 10-PHENANTHROLINE, N-(PARA-SUBSTITUTED PHENYL) GLYCINES WITH COPPER(II), NICKEL(II), COBALT(II) AND ZINC(II)
CHEN, RT
MA, ZY
ZKANG, QY
ACTA CHIMICA SINICA, 1984, 42 (10) : 1044 - 1048
[8] LINEAR FREE-ENERGY RELATIONSHIPS BETWEEN STABILITY OF COMPLEX-COMPOUNDS AND STRENGTHS OF ACID AND BASE OF LIGANDS .8. N,N'-BIS(PARA-SUBSTITUTED PHENYL)ETHYLENEDIAMINE-COPPER(II) AND NICKEL(II) SYSTEMS
CHEN, RT
HE, ZB
GU, ZX
ACTA CHIMICA SINICA, 1988, 46 (02) : 121 - 125
[9] Linear free energy relationships between stability of complex and basicity of ligands——Ⅴ.The stability of complex formed from 1,10-phenanthroline,N-(p-substituted phenyl)glycines with copper(Ⅱ),nickel(Ⅱ),cobalt(Ⅱ) and zinc(Ⅱ)
CHEN Rong-Ti(Y.T.Chen) MA Zang-Yun ZHANG Qi-Yan Department of Chemistry
Acta Chimica Sinica(English Edition), 1984, (02) : 128 - 132
[10] LINEAR FREE-ENERGY RELATIONSHIPS BETWEEN STABILITY OF COMPLEX-COMPOUNDS AND STRENGTHS OF ACID AND BASE OF LIGANDS .3. THE STABILITY OF COMPLEX-COMPOUNDS FORMED FROM "N-(META-SUBSTITUTED-PHENYL)GLYCINES WITH COPPER(II) AND NICKEL(II) AND THEIR THERMODYNAMICAL PARAMETERS
CHEN, RT
LIN, HK
ACTA CHIMICA SINICA, 1983, 41 (02) : 103 - 110

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