STUDIES ON 1,2,3-DIAZAPHOSPHOLE Ⅳ REACTION OF 1,2,3-DIAZAPHOSPHOLE WITH ALCOHOLS

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Bao Zhong CAI Lun Tzu LIU Ru Yu CHEN Institute of Elemento-Organic Chemistry
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ppm; data; REACTION OF 1,2,3-DIAZAPHOSPHOLE WITH ALCOHOLS; STUDIES ON 1,2,3-DIAZAPHOSPHOLE;
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Rapid addition of alcohols to 1,2,3-diazaphosphole 1 easily gave tricoordinatedphosphorus compounds,which were sulfurized to tetracoordinated phosphorus compounds.When ethylene glycol and aminoethanol were used separately to react with 1,the tricoordinatedphosphorus compounds which formed,rearranged to pentacoordinated phosphorus compoundsand the substituents at N;affected the rearrangement significantly.
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页码:531 / 534
页数:4
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