Uniform corrosion behavior of FeCrAl alloys in borated and lithiated high temperature water

被引:9
作者
Fangqiang Ning [1 ,2 ]
Xiang Wang [1 ]
Ying Yang [3 ]
Jibo Tan [1 ]
Ziyu Zhang [1 ]
Dan Jia [1 ]
Xinqiang Wu [1 ]
EnHou Han [1 ]
机构
[1] CAS Key Laboratory of Nuclear Materials and Safety Assessment,Liaoning Key Laboratory for Safety and Assessment Technique of Nuclear Materials,Institute of Metal Research,Chinese Academy of Sciences
[2] School of Materials Science and Engineering,University of Science and Technology of China
[3] ATF R&D Project Department,China Nuclear Power Technology Research Institute Co,Ltd
关键词
D O I
暂无
中图分类号
TG172 [各种类型的金属腐蚀];
学科分类号
080503 ;
摘要
The uniform corrosion behavior of model FeCrAl alloys as well as commercial Zircaloy-4 as reference material were investigated in 360℃ borated and lithiated water. The results reveal that FeCrAl alloys exhibited better corrosion resistance than Zircaloy-4. It is found that the oxide films formed on the FeCrAl alloys are composed of outer Fe3O4 layer, inner layer consisting of compact spinel layer and porous spinel layer, and transition layer containing Al-Cr-rich oxides and matrix enriched with Fe°. The spinel oxides in the inner layer are FeFe2-x-y-zCrxAlyMozO4. The corrosion mechanism of FeCrAl alloys in high temperature water is discussed.
引用
收藏
页码:136 / 144
页数:9
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