MONTE CARLO STUDY ON THE CRITICAL ADSORPTION POINT OF BONDFLUCTUATED POLYMER CHAINS TETHERED ON ADSORBING SURFACES

被引:0
作者
陆文琴
机构
[1] DepartmentofPhysics,ZhejiangUniversity
关键词
Critical adsorption; Polymer chain; Bond fluctuation model; Scaling; Monte Carlo;
D O I
暂无
中图分类号
O647.3 [吸附];
学科分类号
070304 ; 081704 ;
摘要
<正>The behavior of three-dimensional bond fluctuation model chains tethered on an adsorbing fiat surface was simulated by the Monte Carlo method.The dependence of the number of surface contacts M on the interaction strengthεand the chain length N was investigated by a finite-size scaling law M = Nφ[a0 +a1Nl/vκ+ O((Nl/vκ)2)]forεnear the critical adsorption pointεc,i.e.,κ=(ε-εc)/εc closes to 0.The critical adsorption point was estimated to beεc=0.93,and the exponentsφ= 0.49 and l/v= 0.57.
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页码:109 / 114
页数:6
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[1]  
Livne,S,and Meirovitch,H. J Chem.Phys . 1988