A NOVEL SCISSION OF ALKYL-CARBONYL C-C BOND BY ALKYL p-HYDROXYPHENYL KETONES

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Peng GAO
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A NOVEL SCISSION OF ALKYL-CARBONYL C-C BOND BY ALKYL p-HYDROXYPHENYL KETONES;
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Methyl, ethyl, n-propyl, and benzyl p-hydroxyphenyl ketones and 6-hydroxy-1-tetralone are shown under the condition of ethylene ketal formation to undergo alkyl-carbonyl C-C bondscission, but not with p-hydroxybenzophenone, p-hydroxyisobutyrophenone, and 5-hydroxy-1-indanone. It is suggested that the scissiou is preceded by an aldol condensation.
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页码:489 / 492
页数:4
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