Competitive Nucleation and Rapid Growth of Co-Si Intermetallic Compounds during Eutectic Solidification under Containerless Processing Condition

被引:0
作者
Wenjing Yao1)
机构
关键词
Liquid-solid transition; Competitive nucleation; Intermetallic compound; Undercooling;
D O I
暂无
中图分类号
TG111.4 [金属的液体结构和凝固理论];
学科分类号
0702 ; 070205 ;
摘要
The liquid-solid transitions of (Co2Si+CoSi) and (CoSi+CoSi2) eutectic alloys were realized in drop tube and the rapid eutectic growth mechanism of intermetallic compounds was examined. The experimental and calculated results indicate that with increasing Co content, the intermetallic compound prefers nucleating primarily. The eutectic microstructures experience the transitions of ’lamellar-anomalous-divorced’ eutectic with undercooling. In undercooled state, the growth of CoSi intermetallic compound always lags behind others, and no matter how large the undercooling is, this intermetallic compound grows under the solutal diflusion control. The calculated coupled zone demonstrates that (Co2Si+CoSi) eutectic can form within certain undercooling regime, when the composition is in the range from 23.6% to 25.4% Si. And the calculated coupled zone of (CoSi+CoSi2) covers a composition range from 40.8% to 43.8% Si.
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页码:1077 / 1082
页数:6
相关论文
共 2 条
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  • [2] Solidification process and heat transfer analysis of gas-atomized alloy droplets during spray forming .2 Lee E S,Ahn S. Acta Metall Mater . 1994