The Sulfinatodehalogenation Reaction of α,α-Difluorobenzyl Halides with Sodium Dithionite

被引：0

作者：

Jin Tao LIU

He Jun LU Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Fenglin Lu Shanghai ^{[354
,200032
]}

机构：

来源：

Chinese Chemical Letters | 2000年 / 03期

关键词：

Sulfinatodehalogenation; Sodium dithionite; α; α-Difluorobenzyl halide; Alkene;

D O I：

暂无

中图分类号：

O621 [有机化学一般性问题];

学科分类号：

070303 ; 081704 ;

摘要：

The sulfinatodehalogenation reaction of α,α-difluorobenzyl handes, ArCF2X （Ar = CAFS, C6H5; X = Br, I ）, with sodium dithionite took place readily in aqueous acetonitrile under mild conditions. giving the corresponding sodium sulfinate. The 1: 1 adducts were obtained when alkenes were added to the reaction system in some cases.

引用

页码：189 / 190

页数：2