Syntheses and Crystal Structures of Two Novel Cobalt(Ⅱ) Complexes with 2-Amino-5-substituted-1,3,4-thiadiazole as Ligands

被引：0

作者：

安悦 ^{[1
]}

牟萍萍 ^{[1
]}

郭志萍 ^{[1
]}

周光华 ^{[1
]}

机构：

[1] College of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian 116029, China

来源：

Chinese Journal of Structural Chemistry | 2009年 / 05期

关键词：

1; 3; 4-thiadiazole; synthesis; crystal structure;

D O I：

10.14102/j.cnki.0254-5861.2009.05.018

中图分类号：

O627.8 [第Ⅷ族元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

Two novel cobalt(Ⅱ) compounds were obtained and characterized by X-ray single-crystal diffraction,IR,1H NMR and elemental analysis.Compound 1 crystallizes in monoclinic,space group P21/n,with a = 18.046(4),b = 11.335(3),c = 19.157(5) ,β = 92.707(3)o,Z = 4,V = 3914.4(16) 3,Mr = 968.56,Dc = 1.644 g/cm3,μ = 1.378 mm-1,F(000) = 1960,the final R = 0.0367 and wR = 0.0895.The crystal of compound 2 is of monoclinic,space group P21/c with a = 8.7253(10),b = 10.9031(13),c = 18.235(2) ,β = 93.2210(10)o,Z = 4,V = 1732.0(3) 3,Mr = 464.21,Dc = 1.780 g/cm3,μ = 1.560 mm-1,F(000) = 932,the final R = 0.0322 and wR = 0.0743.

引用

页码：607 / 611

页数：5

共 4 条

[1]

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[2]

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[4]

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