PREPARATION OF POLYVINYLAMINE RESIN AND ITS APPLICATION IN RESOLUTION OF DL-AMINO ACID

被引：0
|
作者：
袁直
金仁华
何炳林
机构：
[1] Institute of Polymer Chemistry
[2] Nankai University
[3] PRC
[4] Tianjin 300071
[5] Beijing Institue of Chemical Technology
来源：
Chinese Science Bulletin | 1990年 / 09期
基金：
中国国家自然科学基金;
关键词：
Hofmann degradation; resolution; chirai asymmetric resin;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The preparation of linear polyvinylamine from acrylamide has been published in literature. However, the preparation of crosslinked polyvinylamine from crosslinked polyacrylamide by Hofmann degradation so far has not been reported. Our aim is to make crosslinked polyvinylamine for the resolution of DL-amino adds. The procedure is to graft L-proline on the polyamine and then complex it with Cu(Ⅱ). This asymmetric resin is used as a support for the resolution of DL-amino acids with column chromatographic method.
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页码：736 / 739
页数：4
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