PREPARATION OF POLYVINYLAMINE RESIN AND ITS APPLICATION IN RESOLUTION OF DL-AMINO ACID

被引：0
|
作者：
袁直
金仁华
何炳林
机构：
[1] Institute of Polymer Chemistry
[2] Nankai University
[3] PRC
[4] Tianjin 300071
[5] Beijing Institue of Chemical Technology
来源：
Chinese Science Bulletin | 1990年 / 09期
基金：
中国国家自然科学基金;
关键词：
Hofmann degradation; resolution; chirai asymmetric resin;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The preparation of linear polyvinylamine from acrylamide has been published in literature. However, the preparation of crosslinked polyvinylamine from crosslinked polyacrylamide by Hofmann degradation so far has not been reported. Our aim is to make crosslinked polyvinylamine for the resolution of DL-amino adds. The procedure is to graft L-proline on the polyamine and then complex it with Cu(Ⅱ). This asymmetric resin is used as a support for the resolution of DL-amino acids with column chromatographic method.
引用
收藏
页码：736 / 739
页数：4
相关论文
共 50 条
  • [1] PREPARATION OF POLYVINYLAMINE RESIN AND ITS APPLICATION IN RESOLUTION OF DL-AMINO ACID
    YUAN, Z
    JIN, RH
    HE, BL
    CHINESE SCIENCE BULLETIN, 1990, 35 (09): : 736 - 739
  • [2] RESOLUTION OF DL-AMINO ACIDS BY OPTICALLY ACTIVE ION EXCHANGE RESIN
    SUDA, H
    HOSONO, Y
    HOSOKAWA, Y
    SETO, T
    KOG KAGAKU ZASSHI, 1970, 73 (06): : 1250 - &
  • [3] OPTICAL RESOLUTION OF DL-AMINO ACID MENTHYL ESTER DERIVATIVES BY PAPER CHROMATOGRAPHY
    AKIYAMA, I
    HAYAKAWA, A
    ONAYA, M
    TSUZUKI, Y
    CHEMISTRY LETTERS, 1972, (04) : 269 - +
  • [4] CELLULOSE CONFORMATION RESPONSIBLE FOR RESOLUTION OF DL-AMINO ACIDS
    YUASA, S
    SHIMADA, A
    ISOYAMA, M
    FUKUHARA, T
    ITOH, M
    CHROMATOGRAPHIA, 1986, 21 (02) : 79 - 82
  • [5] Kinetic calculations in the enzymatic resolution of DL-amino acids
    Bódalo, A
    Gómez, JL
    Gómez, E
    Bastida, J
    León, G
    Máximo, MF
    Hidalgo, AM
    Montiel, MC
    ENZYME AND MICROBIAL TECHNOLOGY, 1999, 24 (07) : 381 - 387
  • [6] Racemic Resolution of some dl-Amino Acids using Aspergillus fumigatusl-Amino Acid Oxidase
    Susmita Singh
    Binod K. Gogoi
    Rajib L. Bezbaruah
    Current Microbiology, 2011, 63
  • [7] OPTICAL RESOLUTION OF DL-AMINO ACIDS BY PREFERENTIAL CRYSTALLIZATION PROCEDURE
    YAMADA, S
    YAMAMOTO, M
    CHIBATA, I
    JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (26): : 4408 - 4412
  • [8] Resolution of DL-amino acids on a native cellulose column and a plausible mechanism for their resolution
    Yuasa, S
    Fukuhara, T
    Isoyama, M
    Tanaka, M
    Shimada, A
    BIOMEDICAL CHROMATOGRAPHY, 1997, 11 (05) : 276 - 279
  • [9] Resolution of DL-Amino Acids on a Native Cellulose Column and a Plausible Mechanism for their Resolution
    Yuasa, S.
    Fukuhara, T.
    Isoyama, M.
    Tanaka, M.
    Biomedical Chromatography, 11 (05): : 276 - 279
  • [10] Racemic Resolution of some DL-Amino Acids using Aspergillus fumigatus L-Amino Acid Oxidase
    Singh, Susmita
    Gogoi, Binod K.
    Bezbaruah, Rajib L.
    CURRENT MICROBIOLOGY, 2011, 63 (01) : 94 - 99
12345