In this paper, a new complex {Mo[SCN(CH)]}{FeCl}{CHCHSSCHCH} is syn-thesized by the reaction of MoCl, FeCl, PhCHSH and diethyldithiocarbamate (DTC)in MeOH. The complex is characterized by X-ray, IR, UV-visible, reflection spectra, themeasurements of magnetic susceptibility, differential thermal and elemental analyses. The crystal of triadic complex containing multi-bond species is quite stable and rare.