CRYSTAL STRUCTURE AND NLO PROPERTIES OF 4,4' -DIAMIN-ODIPHENYLSULFONE (DAPS)

被引：0
|
作者：
Su Gen-Bo Pan Feng He You-Ping Guo Shou-WuFujian Institute of Research on the Structure of Matter
机构：
来源：
结构化学 | 1992年 / 04期
关键词：
NLO; DAPS; DIAMIN-ODIPHENYLSULFONE; CRYSTAL STRUCTURE AND NLO PROPERTIES OF 4,4; SHG;
D O I：
10.14102/j.cnki.0254-5861.1992.04.014
中图分类号：
学科分类号：
摘要：
4, 4’-Diaminodiphenylsulfone (DAPS) (NH2C6H4)2SO2, Mr= 248. 3, orthorhombic, space group P212121, a = 8. 057(2), b = 25. 554(6), c = 5. 759(2)(?), V = 1185. 7(6)(?)3, Z = 4, Dc=1. 39g/cm, λ(MoKa) = 0. 71069(?) , μ= 2. 51cm-1, F (000) = 520, T = 296K, R = 0. 044 for 1022 observed reflections (I >3σ(I)). In the crystal there is one intermolecular hydrogen bond O(2)a…H(10)b- N(1)b between molecule (a) and (b), with Oa…Nbdistance of 2. 86(?) and Oa…Hb- N(1)b angle of 161. 7°, which is formed between the - NH2 group of molecule (b) and the atom. O(2) of the molecule (a). A large dihefral angle (78. 31°) exists between the two phenyl planes. Its SHG efficiency of crystalline powders is about 2. 5×KDP and the cut-off wavelength is 335nm in 0. 1mM ethanol solution.
引用
收藏
页码：293 / 296
页数：4
相关论文
共 50 条
  • [21] Crystal structure of zinc(II) 4,4′-oxybis(benzoate)
    Tao, J
    Yin, X
    Huang, RB
    Zheng, LS
    MAIN GROUP METAL CHEMISTRY, 2002, 25 (08): : 523 - 524
  • [22] Crystal structure of catena-(4,4′-bipyridine)disalicylatozinc
    Li, W
    Tong, ML
    Chen, XM
    Ng, SW
    MAIN GROUP METAL CHEMISTRY, 2001, 24 (11): : 799 - 800
  • [23] Crystal structure of 4,4′-(diazenediyl)dipyridinium nitrate perchlorate
    Qiu, Qi-Ming
    Song, Jian-Biao
    Dong, Ai-Guo
    Li, Chuan-Tao
    Zheng, Zhi-Yuan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 897 - +
  • [24] A new one-dimensional 4,4′-bipy-bridged compound [Mn(hfac)2(4,4′-bipy)]n (hfac = hexafluoroacetetylacetonato;: 4,4′-bipy = 4,4′-bipyridine).: Synthesis, crystal structure and magnetic properties
    Shen, HY
    Liao, DZ
    Jiang, ZH
    Yan, SP
    Sun, BW
    Wang, GL
    Yao, XK
    Wang, HG
    POLYHEDRON, 1998, 17 (11-12) : 1953 - 1957
  • [25] Synthesis and crystal structure of a new organic compound: Bis(4,4′-diaminodiphenylmethane) (4,4′-diammoniodiphenylmethane) dichloride monohydrate
    W. Wamani
    M. Belhouchet
    T. Mhiri
    Crystallography Reports, 2013, 58 : 111 - 114
  • [26] Synthesis, characterization and crystal structure of one Mn(II) complex with 4,4′-bisimidazolylbiphenyl and 4,4′-sulfonyldibenzoic acid
    Zhang, Chun-Li
    Qin, Ling
    Zheng, He-Gen
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 34 : 34 - 36
  • [27] Synthesis and crystal structure of a new organic compound: Bis(4,4′-diaminodiphenylmethane) (4,4′-diammoniodiphenylmethane) dichloride monohydrate
    Wamani, W.
    Belhouchet, M.
    Mhiri, T.
    CRYSTALLOGRAPHY REPORTS, 2013, 58 (01) : 111 - 114
  • [28] Characterization, crystal structure determination, and luminescent properties of [Pd(4,4′-bit)Cl2]
    A. Ebadi
    S. Shojaei
    Journal of Structural Chemistry, 2017, 58 : 1457 - 1463
  • [29] Characterization, crystal structure determination, and luminescent properties of [Pd(4,4'-bit)Cl2]
    Ebadi, A.
    Shojaei, S.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 58 (07) : 1457 - 1463
  • [30] Crystal structure, sorption properties, and electronic structure of flexible MOF, (Ni-4,4′azopyridine)[Ni(CN)4]
    Wong-Ng, W.
    McCandless, G. T.
    Culp, J. T.
    Lawson, M.
    Chen, Y. S.
    Siderius, D. W.
    Chen, Y. P.
    Li, L.
    SOLID STATE SCIENCES, 2021, 118
12345