InteractionofEachComponentinNi-Ln2O3/γ-Al2O3System

被引:0
作者
郝茂荣
冯文林
安智华
机构
关键词
rare earths; NiLn 2O 3/γ Al 2O 3 catalyst; methanation; rare earth promoter effects;
D O I
暂无
中图分类号
O614 [金属元素及其化合物];
学科分类号
070301 ; 081704 ;
摘要
The surface functions produced by adding 14 rare earth oxides in Ni/γ Al 2O 3 system were determined by BET, gas chromatography, infrared spectroscopy, XRD, SEM, X ray electronic energy spectrum etc, and researched contrastively. The results show that the addition of rare earth oxides changes the property of catalyst surface. It is of benefit to increasing the number of active center of the catalyst and the surface acidity of the catalyst, decreasing the surface carbon deposit during the reaction. Moreover, the addition of rare earth oxides influences the electronic state of nickel atoms on the surface directly and produces electronic effect. The effect is different for each rare earth element.
引用
收藏
页码:255 / 259
页数:5
相关论文
共 5 条
[1]  
XIE You-chang,QIAN Min-xie,TANG You-qi.Influence of additive La2O3 to dispersity and thermal stability of nickel in methanation catalyst. Chinese Science . 1983
[2]  
LIAO Qiao-li,LIANG Zhen-cheng,QIN Yong-ning,et al.Promotion of lanthanum-cerium oxides to the activity of nickel catalyst. Journal of Computational Mathematics . 1995
[3]  
YANG Xi-yao.Study on the electronic state on the surface of metal catalyst by the competitive hydrogenation method. Petrochemical Engineering . 1986
[4]  
ZHANG Yu-fen,XIE You-chang,ZHANG Yang,et al.Study on the exsisting state on the supporter of fluoride and its reductive performance. Chinese Science . 1986
[5]  
YU Li-qin,LI Xuan-wen.Study method of solid catalyst. Petrochemical Engineering . 2000