Kinetic Study on the Exothermic Decomposition Reaction of 2,4,6,8-Tetranitro-2,4,6,8-tetraazabicyclo[3,3,1]onan-3,7-dione

被引：0

作者：

胡荣祖

宋纪蓉

赵凤起

王伯周

高胜利

朱春华

陈沛

罗阳

宁斌科

陈三平

史启祯

机构：

[1] Xi'an Modern Chemistry Research Institute,Department of Chemistry, Northwest University, Xi'an, Shaanxi , China,Xi'an Modern Chemistry Research Institute,Xi'an Modern Chemistry Research Institute,Department of Chemistry, Northwest University, Xi'an, Shaanx

[2] Department of Chemistry, Northwest University, Xi'an, Shaanxi , China, Xi'an, Shaanxi China, Xi'an, Shaanxi China, Xi'an, Shaanxi China, Xi'an, Shaanxi China, Xi'an, Shaanxi China, Xi'an, Shaanxi China, Xi'an, Shaanxi China

来源：

Chinese Journal of Chemistry | 2004年 / 10期

关键词：

decomposition; 2; 4; 6; 8-tetranitro-2; 8-tetraazabicyclo[3; 1]nonan-3; 7-dione; kinetics;

D O I：

暂无

中图分类号：

O643.1 [化学动力学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetic parameters of the exothermic decomposition reaction of the title compound in a tempera-ture-programmed mode have been studied by means of DSC. The empirical kinetic model function in differential form, apparent activation energy (Ea) and pre-exponential factor (A) of this reaction are (1-)0.222, 225.8 kJmol-1 and 1020.21 s-1, respectively. The critical temperature of thermal explosion of the compound is 224.9 ℃.

引用

页码：1083 / 1086

页数：4