Synthesis and characterization of novel chiral diporphyrins and their dimetal complexes

被引：0
|
作者：
李早英
梁江林
李聪
机构：
[1] Department of Chemistry
[2] Wuhan University
[3] Hubei 430072
[4] China
来源：
Chinese Journal of Chemistry | 2000年 / 04期
基金：
中国国家自然科学基金;
关键词：
Chiral diporphyrin; metalloporphyrin; synthesis; structure characterization;
D O I：
暂无
中图分类号：
O621 [有机化学一般性问题];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of chiral 2,2’-biamino-1,1’-binaphthalene (R or 5) with monosubstituted porphyrin 1b and 2b-c afforded novel chiral diporphyrins 3a-c and 4a-c. Their dimetal complexes [(M)2DiPor] have also been prepared. Both structures have been identified by MS, IR, UV-visible, 1H NMR spectra and elemental analysis. These novel chiral compounds show very high optical activities.
引用
收藏
页码：565 / 570
页数：6
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