Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters

被引：0

作者：

JianJun Dai ^{[1
,2
]}

XinXin Teng ^{[1
]}

Wen Fang ^{[1
]}

Jun Xu ^{[1
,2
]}

HuaJian Xu ^{[1
,2
]}

机构：

[1] School of Food and Biological Engineering, Hefei University of Technology

[2] Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, Hefei University of Technology

来源：

ChineseChemicalLetters | 2022年 / 33卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal-or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical conditions. This reaction exhibits broad substrate scope, good functional group tolerability, and easy scalability.

引用

页码：1555 / 1558

页数：4

共 43 条

[31]

Zinc-catalyzed borylation of primary, secondary and tertiary alkyl halides with alkoxy diboron reagents at room temperature[J] . Bose Shubhankar Kumar,Fucke Katharina,Liu Lei,Steel Patrick G,Marder Todd B.Angewandte Chemie （International ed. in English） . 2014 (7)

[32]

Iron-Catalyzed Borylation of Alkyl, Allyl, and Aryl Halides: Isolation of an Iron（I） Boryl Complex[J] . Robin B. Bedford,Peter B. Brenner,Emma Carter,Timothy Gallagher,Damien M. Murphy,Dominic R. Pye.Organometallics . 2014 (21)

[33] Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon-Boron Bonds [J].

Dudnik, Alexander S. ;

Fu, Gregory C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (25) :10693-10697

[34] Alkylboronic Esters from Palladium- and Nickel-Catalyzed Borylation of Primary and Secondary Alkyl Bromides [J].

Yi, Jun ;

Liu, Jin-Hui ;

Liang, Jun ;

Dai, Jian-Jun ;

Yang, Chu-Ting ;

Fu, Yao ;

Liu, Lei .

ADVANCED SYNTHESIS & CATALYSIS, 2012, 354 (09) :1685-1691

[35] Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides [J].

Ito, Hajime ;

Kubota, Koji .

ORGANIC LETTERS, 2012, 14 (03) :890-893

[36] Alkylboronic Esters from Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides [J].

Yang, Chu-Ting ;

Zhang, Zhen-Qi ;

Tajuddin, Hazmi ;

Wu, Chen-Cheng ;

Liang, Jun ;

Liu, Jing-Hui ;

Fu, Yao ;

Czyzewska, Maria ;

Steel, Patrick G. ;

Marder, Todd B. ;

Liu, Lei .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (02) :528-532

[37] Modern strategies in electroorganic synthesis [J].

Yoshida, Jun-ichi ;

Kataoka, Kazuhide ;

Horcajada, Roberto ;

Nagaki, Aiichiro .

CHEMICAL REVIEWS, 2008, 108 (07) :2265-2299

[38] The development of enantioselective rhodium-catalysed hydroboration of olefins [J].

Carroll, AM ;

O'Sullivan, TP ;

Guiry, PJ .

ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (05) :609-631

[39]

Catalytic Asymmetric Hydroboration: Recent Advances and Applications in Carbon?Carbon Bond‐Forming Reactions[J] . Eur. J. Org. Chem. . 2003 (24)

[40] Bortezomib [J].

Paramore, A ;

Frantz, S .

NATURE REVIEWS DRUG DISCOVERY, 2003, 2 (08) :611-612

← 1 2 3 4 5 →