Anodic hydrogen evolution on Mg

被引:0
|
作者
Yang Li [1 ]
Zhiming Shi [1 ]
Xingrui Chen [1 ]
Andrej Atrens [1 ]
机构
[1] School of Mechanical and Mining Engineering, Centre for Advanced Materials and Processing, The University of Queensland
基金
澳大利亚研究理事会;
关键词
D O I
暂无
中图分类号
TG172 [各种类型的金属腐蚀];
学科分类号
080503 ;
摘要
We measured the anodic hydrogen evolution rates for various applied anodic current densities and estimated the corresponding cathodic hydrogen evolution rates.The estimated cathodic hydrogen evolution rates were less than the measured anodic hydrogen evolution rates,contradicting the enhanced catalytic activity mechanism of Mg corrosion.In addition,this model was contradicted by the measured apparent Mg valence of 1.2±0.1.In contrast,the uni-positive Mg+mechanism of Mg corrosion was supported by (i) the apparent Mg valence of 1.2±0.1,and (ii) the fact that the measured anodic hydrogen evolution rate increased with increasing weight loss rate.
引用
收藏
页码:2049 / 2062
页数:14
相关论文
共 50 条
  • [1] Anodic hydrogen evolution on Mg
    Yang Li
    Zhiming Shi
    Xingrui Chen
    Andrej Atrens
    Journal of Magnesium and Alloys, 2021, 9 (06) : 2049 - 2062
  • [2] Anodic hydrogen evolution on Mg
    Li, Yang
    Shi, Zhiming
    Chen, Xingrui
    Atrens, Andrej
    JOURNAL OF MAGNESIUM AND ALLOYS, 2021, 9 (06) : 2049 - 2062
  • [3] The anodic surface film and hydrogen evolution on Mg
    Song, Guang-Ling
    Unocic, Kinga A.
    CORROSION SCIENCE, 2015, 98 : 758 - 765
  • [4] Hydrogen Evolution During Anodic Polarization of Mg Alloyed with Li, Ca, or Fe
    Samaniego, A.
    Birbilis, N.
    Xia, X.
    Frankel, G. S.
    CORROSION, 2015, 71 (02) : 224 - 233
  • [5] On the Fe Enrichment during Anodic Polarization of Mg and Its Impact on Hydrogen Evolution
    Lysne, D.
    Thomas, S.
    Hurley, M. F.
    Birbilis, N.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (08) : C396 - C402
  • [6] Introductory lecture on corrosion chemistry: a focus on anodic hydrogen evolution on Al and Mg
    Frankel, G. S.
    Fajardo, S.
    Lynch, B. M.
    FARADAY DISCUSSIONS, 2015, 180 : 11 - 33
  • [7] The Mechanism of Hydrogen Evolution During Anodic Polarization of Aluminium
    Curioni, M.
    Scenini, F.
    ELECTROCHIMICA ACTA, 2015, 180 : 712 - 721
  • [8] Corrosion mechanism and hydrogen evolution on Mg
    Thomas, S.
    Medhekar, N. V.
    Frankel, G. S.
    Birbilis, N.
    CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2015, 19 (02): : 85 - 94
  • [9] On hydrogen embrittlement of Mg under free and anodic corrosion in chloride electrolyte
    Nazarov, A.P.
    Yurasova, T.A.
    Gubin, V.V.
    Buryak, A.K.
    Glazunov, M.P.
    Zashchita Metallov, 1993, 29 (03): : 392 - 397
  • [10] Research progress in anodic hydrogen evolution of magnesium electrochemistry corrosion
    Liu Yu-xiang
    Zhu Sheng
    Han Bing-yuan
    CAILIAO GONGCHENG-JOURNAL OF MATERIALS ENGINEERING, 2020, 48 (10): : 17 - 27