Enhancement of upconversion luminescence due to the formation of nanocrystals in Er3+-doped tellurite glasses

被引:0
作者
周刚 [1 ]
戴世勋 [2 ]
于春雷 [1 ]
张军杰 [3 ]
汪国年 [1 ]
温磊 [3 ]
姜中宏 [3 ]
机构
[1] Laser Glass Laboratory,Shanghai Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Shanghai 201800 Graduate School of the Chinese Academy of Sciences,Beijing 100049  2. Laser Glass Lab
基金
中国国家自然科学基金;
关键词
doped tellurite glasses; Enhancement of upconversion luminescence due to the formation of nanocrystals in Er;
D O I
暂无
中图分类号
TQ171.1 [基础理论];
学科分类号
0805 ; 080502 ;
摘要
Optically transparent Er3+-doped tellurite-based nanocrystallized glasses with the composition of 70TeO2·15Li2O·15Nb2O5·0.5Er2O3 (mol) have been prepared by a conventional melting quenching and the subsequent heat treatment processes. The sizes of grown nanocrystals in glass matrix appear to be 35-50 nm from the X-ray diffraction (XRD) measurement. The microhardness measurement shows that the Vickers hardness values of the nanocrystallized tellurite glasses are larger (33%-62%) than those in the base glass. The Raman spectra imply that the maximum phonon energy of the based glass decreases and shifts from 668 to 638 cm-1 after heat-treatment. Visible upconversion luminescence and infrared luminescence of the base glass and heat-treated glasses under 980-nm laser diode (LD) excitation are investigated. The 524-, 546- and 656-nm upconversion intensities by 980-nm pumping increase significantly.
引用
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页码:36 / 38
页数:3
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