Crafting of plasmonic Au nanoparticles coupled ultrathin BiOBr nanosheets heterostructure:steering charge transfer for efficient CO2 photoreduction

Integrating semiconductor photocatalysts with outstanding visible light absorption and fast surface/interface charge transfer kinetics is still an enormous challenge for efficient CO2photoreduction. In this work, the Au nanoparticles have been coupled with ultrathin BiOBr nanosheets, the formed heterostructure(Au/BiOBr) possesses a localized surface plasmon resonance(LSPR) and enhances the visible light absorption ability, as well as forms a fast charge transport channel on the interface between Au and BiOBr. Thus, the heterostructure photocatalyst exhibits higher photocatalytic CO2to CO performance(135.3/16.43 μmol g-1) than that of BiOBr(89.0/6.46 μmol g-1) under 300 W Xe lamp and visible light(λ > 400 nm) irradiation for 5 h, respectively. Finally, the in situ FT-IR spectroscopy revealed CO2photoreduction process and found that the *COOH is the key intermediate for CO2to CO. This work provides an effective method to construct multielectron transfer scheme for efficient photocatalytic CO2reduction.