Diels-Alder Reactions of 3-Carboethoxy- and 3-Carbonitrile-2-Cyclohexen-1-one

被引：0
|
作者：
Wen Qian YANG
Shi Zhi CHEN
Liang HUANG(Institute of Materia Medica
机构：
来源：
ChineseChemicalLetters | 1998年 / 03期
关键词：
Diels-Alder reaction; base-induced isomerization;
D O I：
暂无
中图分类号：
O621 [有机化学一般性问题];
学科分类号：
070303 ; 081704 ;
摘要：
Aluminum chloride induced Diels-Alder reactions of 3-carboethoxy- and 3-carbonitrile-2-cyclohexen-1-one with cyclopentadiene, isoprene and (E)-piperylene were described. Thestereochemistry of the adducts were confirmed by 2D-NMR spectroscopy and isomerizationreactions.
引用
收藏
页码：233 / 234
页数：2
相关论文
共 50 条
  • [21] ON THE REACTIVITY OF SILAETHENE ME2SI=C(SIME3)2 - STEREOSPECIFICITY OF DIELS-ALDER REACTIONS WITH HEXADIENES
    WIBERG, N
    FISCHER, G
    WAGNER, S
    CHEMISCHE BERICHTE, 1991, 124 (04) : 769 - 771
  • [22] Synthesis of 1-methoxypoly(oxyethylene)benzocyclobutene and its Diels-Alder reactions
    Herati, RS
    Herati, RS
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (08) : 1934 - 1938
  • [23] Synthesis of 2,4-disubstituted 3-chlorofurans and the effect of the chlorine substituent in furan Diels-Alder reactions
    Ram, Ram N.
    Kumar, Neeraj
    TETRAHEDRON LETTERS, 2008, 49 (05) : 799 - 802
  • [24] A theoretical study of intramolecular Diels-Alder reactions, diene-(CH2)n-dienophile (n=1, 2, 3 and 4)
    Vijaya, R
    Sastry, GN
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2002, 618 (03): : 201 - 208
  • [25] Exo selectivity and the effect of disubstitution in the Diels-Alder reactions of butadiene with 3,3-disubstituted cyclopropenes
    Gosse, TL
    Poirier, RA
    CANADIAN JOURNAL OF CHEMISTRY, 2004, 82 (11) : 1589 - 1596
  • [26] Diels-Alder modification of monoterpenes and Alder-ene synthesis involving 3-methyl-3-cyanocyclopropene
    R. V. Ashirov
    S. A. Appolonova
    V. V. Plemenkov
    Chemistry of Natural Compounds, 2006, 42 : 434 - 438
  • [27] C2-Symmetric bipyrrolidines as organocatalysts for asymmetric Diels-Alder reactions
    Ma, Yuanhui
    Zhang, Yong Jian
    Jin, Shangbin
    Li, Qiqi
    Li, Chenguang
    Lee, Junseong
    Zhang, Wanbin
    TETRAHEDRON LETTERS, 2009, 50 (52) : 7388 - 7391
  • [28] Diels-Alder modification of monoterpenes and Alder-ene synthesis involving 3-methyl-3-cyanocyclopropene
    Ashirov, R. V.
    Appolonova, S. A.
    Plemenkov, V. V.
    CHEMISTRY OF NATURAL COMPOUNDS, 2006, 42 (04) : 434 - 438
  • [29] Synthesis of (E)-1-Benzyloxy-3-fluoro-1,3-butadiene: A Novel Fluorinated Diene for Diels-Alder Reactions
    Hayashi, Tsuyoshi
    Usuki, Yoshinosuke
    Wakamatsu, Yosuke
    Iio, Hideo
    SYNLETT, 2010, (19) : 2843 - 2846
  • [30] Recyclable tetraarylphosphonium supported chiral imidazolidin-4-one organocatalyst for Diels-Alder reactions
    Lin, Zihan
    Chen, Zuxing
    Yang, Guichun
    Lu, Cuifen
    CATALYSIS COMMUNICATIONS, 2013, 35 : 1 - 5
12345