CRYSTAL STRUCTURE OF Fe4S4[SC（CH3）3]4[（C4H9）4N]2

被引：0

作者：

Hu Ning-Hai Liu Yong-ShengChangchun Institute of Applied Chemistry

机构：

来源：

结构化学 | 1991年 / 02期

关键词：

Fe; C4H9; CH3; CRYSTAL STRUCTURE OF Fe4S4[SC;

D O I：

10.14102/j.cnki.0254-5861.1991.02.008

中图分类号：

学科分类号：

摘要：

FeS[SC（CH）][（C1H）,Mr=1193. 23,tetragonal,142d,a = 23. 272（2）, c= 13. 080（5） A ,V=7084（3） A3,Z=4,DC=1. 12g·cm-3,UUUU（MoKa） = 10. 8cm-1,F（000） = 2568,R=0. 058 for 1005 observed reflections. The cluster anion contains a cubane-type Fe4S4 core compressed along the 4 axis which is crystallographically imposed. Compared to other salts with different cations ,the core is subject to slight structural distortions in different crystalline environments and crystallographic symmetry of the anion is related to that of the cation.

引用

页码：117 / 120

页数：4

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