Synthesis and Crystal Structure of α,α,β,β-5,10,15,20-Tetrakis(2-aminophenyl)porphyrin

被引：0

作者：

矫志 ^{[1
]}

王建辉 ^{[1
]}

史秀丽 ^{[1
]}

臧娜 ^{[1
]}

刘阁 ^{[1
]}

阮文娟 ^{[1
]}

朱志昂 ^{[1
]}

机构：

[1] College of Chemistry,Nankai University

来源：

结构化学 | 2008年 / 09期

基金：

中国国家自然科学基金;

关键词：

porphyrin; crystal structure; N-H···π; interactions;

D O I：

10.14102/j.cnki.0254-5861.2008.09.021

中图分类号：

O626.13 [氮杂茂（吡咯）族];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound,α,α,β,β-5,10,15,20-tetrakis(2-aminophenyl)porphyrin,has been obtained and characterized by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system,space group C2/c with a = 31.804(6),b = 19.314(4),c = 12.872(3),β = 90.592(3)°,Z = 4,V = 7907(3) 3,Dc = 1.193 g/cm3,Mr = 1419.67,λ(MoKα) = 0.71073 ,μ = 0.073 mm-1,F(000) = 2984,R = 0.0773 and wR = 0.2045.The crystallographic analysis indicates the existence of N-H···π intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure.

引用

页码：1103 / 1108

页数：6

共 50 条

[21] Synthesis and characterization of some manganese complexes of 5,10,15,20-tetrakis (4-n-dodecylphenyl)porphyrin
Hill, J
Sugino, T
Shimizu, Y
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 332 : 2629 - 2635
[22] Target Prediction of 5,10,15,20-Tetrakis(4′-Sulfonatophenyl)-Porphyrin Using Molecular Docking
Udrea, Ana-Maria
Dinache, Andra
Staicu, Angela
Avram, Speranta
PHARMACEUTICS, 2022, 14 (11)
[23] Organic field effect transistors based on 5,10,15,20-tetrakis(4-pentyloxyphenyl)porphyrin single crystal
Ma, Pan
Chen, Yanli
Cai, Xue
Wang, Hailong
Zhang, Yuexing
Gao, Yingning
Jiang, Jianzhuang
SYNTHETIC METALS, 2010, 160 (5-6) : 510 - 515
[24] An electrochemical quartz crystal microbalance study of 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin electropolymerization process
Tesakova, Mariya, V
Kuzmin, Sergey M.
Parfenyuk, Vladimir
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2019, 23 (11-12) : 1495 - 1504
[25] Crystal structure of (methanol-kappa O)[5,10,15,20-tetrakis(2-aminophenyl)porphyrinato-kappa N-4]zinc(II)-chloroform-methanol (1/1/1)
Leben, Lisa
Naeher, Christian
Herges, Rainer
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1285 - +
[26] Synthesis, characterization and photocatalytic activity of Co(III) 5,10,15,20-tetrakis(carboxyphenyl)porphyrin-supported chitosan
Ghafuri, Hossein
Rahimi, Rahmatollah
Felfelian, Ziba
Rabbani, Mahboubeh
18TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY, 2014,
[27] Zinc(II)-5,10,15,20-tetrakis(alpha-pyridino-m-tolyl)porphyrin Tetrabromide
Ishikawa, Yoshinobu
Yamashita, Takeshi
Fujii, Satoshi
Uno, Tadayuki
MOLBANK, 2009, (04)
[28] Effect of Solvent Polarity on the Spectral Characteristics of 5,10,15,20-Tetrakis(p-hydroxyphenyl)porphyrin
Guo, Hongwei
Liu, Xianhu
Li, Lan
Chang, Yanping
Yao, Wanqing
MOLECULES, 2023, 28 (14):
[29] Surface-type multifunctional sensor based on 5,10,15,20-tetrakis(4′-isopropylphenyl) porphyrin
Muhammad Saleem
Muhammad H. Sayyad
Khasan S. Karimov
Muhammad Yaseen
Mukhtar Ali
Journal of Materials Science, 2009, 44 : 1192 - 1197
[30] Cu 5,10,15,20-Tetrakis(3-aminophenyl)porphyrin Films Obtained via Polymerization Using Electrooxidation or Superoxide Assistance as Initiating Step
Parfenyuk, Vladimir I.
Kuzmin, Sergey M.
Chulovskaya, Svetlana A.
Filimonova, Yuliya A.
MACROHETEROCYCLES, 2024, 17 (03): : 197 - 204

← 1 2 3 4 5 →