Optical properties of electrochemically synthesized polypyrrole thin films:the electrolyte effect

被引：0

作者：

J.V.Thombare ^{[1
]}

S.K.Shinde ^{[1
]}

G.M.Lohar ^{[1
]}

U.M.Chougale ^{[1
]}

S.S.Dhasade ^{[2
]}

H.D.Dhaygude ^{[1
]}

B.P.Relekar ^{[1
]}

V.J.Fulari ^{[1
]}

机构：

[1] Holography and Materials Research Laboratory,Department of Physics,Shivaji University

来源：

Journal of Semiconductors | 2014年 / 06期

关键词：

electrodeposition; polypyrrole; extinction coefficient; refractive index;

D O I：

暂无

中图分类号：

TM914.4 [太阳能电池];

学科分类号：

080502 ;

摘要：

Polypyrrole thin films are prepared by the potentiostatic mode of electrodeposition at C0:7 V versus a saturated calomel electrode(SCE). The polypyrrole films are prepared in the presence of different electrolytes such as: p-toluene sulphonic acid(PTS), oxalic acid and H2SO4. The prepared films are characterized by UV–vis absorption spectroscopy and normal reflectance measurements. The electrochemically synthesized films are semiconductor in nature. The band gap energy of polypyrrole thin films is found to be 1.95, 1.92 and 1.79 eV for H2SO4, oxalic acid and p-toluene sulphonic acid, respectively. The normal reflectance spectroscopy of polypyrrole films shows that the maximum reflectance is in the presence of p-toluene sulphonic acid; this is may be due to a more distinct microstructure than the others. The optical constants such as the extinction coefficient, refractive index, optical conductivity, etc. are calculated and studied with various electrolytes.

引用

页码：5 / 8

页数：4

共 50 条

[31] Effect of electrolyte solvent on the morphology of polypyrrole films: Application to the use of polypyrrole in pH sensors [J].

Carquigny, Stephanie ;

Segut, Olivier ;

Lakard, Boris ;

Lallemand, F. ;

Fievet, Patrick .

SYNTHETIC METALS, 2008, 158 (11) :453-461

[32] SECM investigation of electrochemically synthesized polypyrrole from aqueous medium [J].

El Jaouhari, A. ;

Filotas, D. ;

Kiss, A. ;

Laabd, M. ;

Bazzaoui, E. A. ;

Nagy, L. ;

Nagy, G. ;

Albourine, A. ;

Martins, J. I. ;

Wang, R. ;

Bazzaoui, M. .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2016, 46 (12) :1199-1209

[33] Effect of Laser Treatment on the Optical Properties of Poly(methyl methacrylate) Thin Films [J].

Zahedi, Shima ;

Dorranian, Davoud .

OPTICAL REVIEW, 2013, 20 (01) :36-40

[34] Electrochemically Synthesized Polypyrrole/Graphene Composite Film for Lithium Batteries [J].

Yang, Yang ;

Wang, Caiyun ;

Yue, Binbin ;

Gambhir, Sanjeev ;

Too, Chee O. ;

Wallace, Gordon G. .

ADVANCED ENERGY MATERIALS, 2012, 2 (02) :266-272

[35] The Effect of pH on the Morphology of Electrochemically-grown Polypyrrole Films: An AFM Study [J].

Paramo-Garcia, U. ;

Batina, N. ;

Ibanez, J. G. .

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2012, 7 (12) :12316-12325

[36] SECM investigation of electrochemically synthesized polypyrrole from aqueous medium [J].

A. El Jaouhari ;

D. Filotás ;

A. Kiss ;

M. Laabd ;

E. A. Bazzaoui ;

L. Nagy ;

G. Nagy ;

A. Albourine ;

J. I. Martins ;

R. Wang ;

M. Bazzaoui .

Journal of Applied Electrochemistry, 2016, 46 :1199-1209

[37] Effect of Substrate Properties on Nanostructure and Optical Properties of CdTe Thin Films [J].

Ebrahim Hasani ;

Monir Kamalian ;

Maryam Gholizadeh Arashti ;

Lida Babazadeh Habashi .

Journal of Electronic Materials, 2019, 48 :4283-4292

[38] Effect of Substrate Properties on Nanostructure and Optical Properties of CdTe Thin Films [J].

Hasani, Ebrahim ;

Kamalian, Monir ;

Arashti, Maryam Gholizadeh ;

Habashi, Lida Babazadeh .

JOURNAL OF ELECTRONIC MATERIALS, 2019, 48 (07) :4283-4292

[39] Thickness, Structure, Composition and Optical Properties of Electrochemically Grown Iron Selenide and Iron Diselenide Thin Films [J].

Thanikaikarasan, S. ;

Perumal, R. ;

Thanikaivelan, E. ;

Ahamad, Tansir ;

Alshehri, Saad M. .

JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, 2023, 26 (02) :101-106

[40] Influence of potential on structural, compositional, optical and magnetic properties of electrochemically grown iron selenide thin films [J].

Thanikaikarasan, S. ;

Perumal, R. ;

Marjorie, S. Roji .

JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 848

← 1 2 3 4 5 →