Ring-closure Reaction to Novel Quinoline Derivatives and Their Structural Characterization

被引：0

作者：

吕银祥

蓝碧健

周辉

徐伟

王静梅

黄永明

机构：

[1] Department of Materials Science, Fudan University, Shanghai , China ,Department of Materials Science, Fudan University, Shanghai , China ,Department of Materials Science, Fudan University, Shanghai , China ,Department of Materials Science, Fudan University

[2] Department of Chemistry, Fudan University, Shanghai , China ,Research Center for Analysis and Measurment, Fudan University, Shanghai , China,Department of Chemistry, Fudan University, Shanghai , China

来源：

Chinese Journal of Chemistry | 2004年 / 08期

关键词：

arylaldehyde; arylethylidenemalononitrile; ring closure; X-ray diffraction;

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

In the condensation of arylaldehydes with arylethylidenemalononitriles, it was found that, besides the normal product dienes a, the ring-closure product quinoline derivatives b can be also obtained in 26%—50% yields. The substituent effects were also examined and a possible reaction mechanism was proposed for the formation of b. The X-ray crystal structure of 1b confirms the structure of the ring-closure product.

引用

页码：854 / 858

页数：5

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