Hydrothermal Synthesis and Structure of a Copper（II） Complex, [Cu（4,4'bpy）(H2O)3]SO42H2O

被引：2
|
作者：
LIN Bi-Zhou② LIU Pei-De (Institute of Materials Physical Chemistry
机构：
来源：
结构化学 | 2003年 / 06期
关键词：
hydrothermal synthesis; crystal structure; copper complexes;
D O I：
10.14102/j.cnki.0254-5861.2003.06.009
中图分类号：
O627 [元素有机化合物];
学科分类号：
摘要：
The title complex [Cu(4,4?bpy)(H2O)3]SO42H2O (Mr = 405.86) was synthesized under hydrothermal conditions and its crystal structure has been determined by X-ray diffraction. It crystallizes in the hexagonal system, space group P61 with a = 11.1870(4), c = 21.578(1) ? V = 2338.6(2) ?, Dc = 1.729 g/cm3, Z = 6, m(MoKa) = 1.583 mm-1 and F(000) = 1254. The final R and wR are 0.0253 and 0.0416 for 1458 observed reflections with I≥2s(I), respectively. It was revealed that the square pyramidal Cu(II) sites are linked through 4,4?bipyridine groups, forming infinite one-dimensional chains, with the sulfate anions and lattice water molecules occupying the inter-chain positions. During the electrostatic interactions, there exist O…O hydrogen bonds and p-p stacking interactions between the parallel aromatic bipy rings in the structure.
引用
收藏
页码：673 / 676
页数：4
相关论文
共 50 条
  • [1] Hydrothermal synthesis and structure of a copper(II) complex, [Cu(4,4′-bpy)(H2O)3]SO4-2H2O
    Lin, BZ
    Liu, PD
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (06) : 673 - 676
  • [2] Synthesis, structure and properties of a new copper (II) complex, [Cu2(4,4′-bpy)5(H2O)4](ClO4)4(4,4′-bpy)(DMF)2(H2O)2
    Hu, Feilong
    Yin, Xianhong
    Mi, Yan
    Li, Wanshu
    Tang, Xinping
    Ma, Zhen
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (06) : 720 - 723
  • [3] Hydrothermal synthesis and crystal structure of coordination polymer [Mn(4,4′-bpy)1.5(H2O)3](ClO4)•(4,4′-bpy)(L)•H2O
    Huang Miao-Ling
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (06) : 1059 - 1062
  • [4] Crystal structure of triaqua-4,4′-bipyridinecopper(II) sulfate dihydrate, [Cu(4,4′-bpy)(H2O)3](SO4) • 2H2O
    Yuan, JX
    Hu, ML
    Song, XY
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2003, 218 (01): : 93 - 94
  • [5] Crystal Structure of [Cu(H2O)2(4,4′-bpy)](ClO4)2•(4,4′-bpy)
    Fenghui Liu
    Wanzhi Chen
    Xiaozeng You
    Analytical Sciences, 2002, 18 : 1179 - 1180
  • [6] Crystal structure of [Cu(H2O)2(4,4′-bpy)](ClO4)2•(4,4′-bpy)
    Liu, FH
    Chen, WZ
    You, XZ
    ANALYTICAL SCIENCES, 2002, 18 (10) : 1179 - 1180
  • [7] Hydrothermal Synthesis, Crystal Structure and Magnetic Property of a New Co(II) Complex: [Co(4,4′-bpy)2(H2O)2(4-FBA)2]•(4,4′-bpy)
    Zhang Bi-Song
    Zheng Miao
    Wu Chang-Sheng
    Li Yun-Xia
    Qiu Jian-Ping
    Zheng Yue-Qing
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (04) : 577 - 581
  • [8] Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of the Copper（II） Complex [Cu4O4（phen）4（ClC6H4COO）2（H2O）2]·（H2O）3
    LI Weia② LI Chang-Hongb② YANG Ying-Quna KUANG Yun-Feia a (Department of Chemistry and Materials Science
    结构化学, 2006, (11) : 1331 - 1336
  • [9] Hydrothermal synthesis, crystal structure and electrochemical properties of the copper(II) complex [CU4O4(phen)4(ClC6H4COO)2(H2O)2].(H2O)3
    Li Wei
    Li Chang-Hong
    Yang Ying-Qun
    Kuang Yun-Fei
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (11) : 1331 - 1336
  • [10] Solids with rhombic channels:: Syntheses and crystal structures of [Cu3(NTA)2(4,4′-bpy)2(H2O)2]•9H2O and [{Cu(4,4′-bpy)(H2O)4}{Cu2(NTA)2(4,4′-bpy)}]• 7H2O (NTA = nitrilotriacetate, 4,4′-bpy = 4,4′-bipyridine)
    Wang, QM
    Wu, XT
    Zhang, WJ
    Sheng, TL
    Lin, P
    Li, JM
    INORGANIC CHEMISTRY, 1999, 38 (09) : 2223 - 2226
12345