Hydrothermal Synthesis and Structure of a Novel Coordination Polymer Co3（tma）(pda)2（H2O）3]n·nH2O

被引：0
|
作者：
周秋香
白晓杰
陈乐培
机构：
[1] Institute of Materials Chemistry Langfang Teacher College Langfang Hebei 065000 China
[2] Institute of Materials Chemistry Langfang Teacher College Langfang Hebei 065000 China
来源：
Chinese Journal of Structural Chemistry | 2006年 / 01期
关键词：
coordination polymer; hydrothermal synthesis; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2006.01.009
中图分类号：
O631 [高分子物理和高分子物理化学];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel coordination polymer [Co3(tma)(pda)2(H2O)3]n?nH2O was synthesized by hydrothermal reaction of 3-(3-pyridyl)acrylate acid (pda) and trimesic acid (tma) with CoCl2?6H2O. The structure was characterized by elemental analysis, IR spectroscopy and X-ray single-crystal dif- fraction analysis. It crystallizes in triclinic, space group P 1 with a = 9.569(4), b = 12.562(6), c = 12.666(6) ?, α = 97.321(7), β = 110.295(7), γ = 106.110(7)°, V = 1328.9(10) ?3, Dc = 1.877 g/cm3, Mr = 751.24, Z = 2, μ = 1.930 mm?1, F(000) = 758, the final R = 0.0392 and wR = 0.0837. The diffraction result shows that Co atoms are linked through pda and tma ligands to form an infinite three-dimensional network.
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收藏
页码：49 / 52
页数：4
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