Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers

被引：0

作者：

CHANG GuanJun TANG ShiZhen LUO Xuan WANG Qiang XU Zhe ZHANG Lin LIN RunXiong Key Laboratory of Rubberplastics Ministry of Education Qingdao University of Science and Technology Qingdao China Resarch Center of Laser Fusion China Academy of Engineering Physics Mianyang China College of Engineering Ocean University of China Qingdao China ^{[1
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机构：

来源：

Science in China(Series B:Chemistry) | 2008年 / 03期

关键词：

aromatic dibromides; aromatic diamines; palladium-catalyzed; poly(aryl amine ketone);

D O I：

暂无

中图分类号：

O631.3 [高聚物的化学性质];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of poly(aryl amine ketone)s have been obtained by the condensation polymerization of different aromatic dibromides with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The structures of polymers are characterized by means of FT-IR, 1H NMR spectroscopy, and elemental analysis. The results show an agreement with the proposed structures. DSC and TG measurements show that polymers possess high glass transition temperature (Tg>170℃) and good thermal stability with high decomposition temperatures (TD>450℃). These novel polymers also exhibit good mechanical behaviors and good solubility.

引用

页码：275 / 281

页数：7