Dimethyltin Dichloride-Dibenzyl Sulfoxide,a Compound Crystallizing with Seven Molecules in the Asymmetric Unit

被引：0

作者：

伍锡荣 ^{[1
]}

机构：

[1] Department of Chemistry,University of Malaya

来源：

结构化学 | 2010年 / 29卷 / 10期

关键词：

dimethyltin dichloride–dibenzyl sulfoxide; Z’ (formula unit per asymmetric crystal unit);

D O I：

10.14102/j.cnki.0254-5861.2010.10.020

中图分类号：

O621.21 [];

学科分类号：

070303 ; 081704 ;

摘要：

Dimethyltin dichloride-dibenzyl sulfoxide,((CH3)2SnCl2·O=S(CH2C6H5)2),crystallizes in the orthorhombic space group P212121 with a superstructure of dimensions a = 11.9290(1),b = 19.50490(1),c = 55.7390(6) ; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%.

引用

页码：1584 / 1586

页数：3

共 7 条

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CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (10) : 1584 - 1586
[2] CONSTRAINED REFINEMENT OF COMMENSURATELY MODULATED DIMETHYLTIN DICHLORIDE DIBENZYL SULFOXIDE
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[4] Structure analysis of a phenylpyrazole carboxylic acid derivative crystallizing with three molecules in the asymmetric unit (Z′=3) using X-ray powder diffraction
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POWDER DIFFRACTION, 2019, 34 (02) : 151 - 158
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[7] (Acetylacetonato-κ2O,O′)(2,2′-bi-pyridine-κ2N, N′)iodidocopper(II):a compound with two molecules in the asymmetric unit due to different π-π interactions
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Carvalho, Sandra
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