Syntheses, Structures and Fluorescent Properties of Two 1D Chain Organic Amines and Metal Iodine Organic-inorganic Hybrid Compounds

被引：0

作者：

游秀丽 ^{[1
]}

魏振宏 ^{[2
]}

机构：

[1] Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University

[2] College of Chemistry, Nanchang University

来源：

Chinese Journal of Structural Chemistry | 2019年 / 38卷 / 02期

关键词：

organic-inorganic hybrids; bifunctional amines; metal iodide; crystal structure; fluorescent property;

D O I：

10.14102/j.cnki.0254-5861.2011-2043

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

Two bifunctional amines, 4-（2-aminoethyl）morpholine and histamine, were heated with PbI2 and BiI3 in concentrated HI aqueous solution to give one-dimensional（1D） organicinorganic hybrid compounds [(C6H16N2O)PbI4]n（1） and [(C16H20N20)Bi2I10]（2）, respectively. In 1, the [PbI6] octahedra formed double chain anions through sharing-corner and-edge, and the protonated(C6H16N2O)2+ cations were located at the vicinity of the double chains by hydrogen bonds. In 2, the [BiI6] octahedra firstly formed dimeric [Bi2I10]4- anion through sharing edge, and subsequently, the protonated histamine cations worked as bridge to link alternately with [Bi2I10]4- anion by hydrogen bonds to form organic-inorganic hybrid 1D chains. In addition, compound 1 emitted a green light at the excitation wavelength of 400 nm and the maximum emission wavelength is at 503 nm.

引用

页码：284 / 292

页数：9

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