A facile and efficient method for hydroxylation of azabenzanthrone compounds

被引：0
作者：
Fang Xian Ning
机构：
来源：
Chinese Chemical Letters | 2011年 / 22卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Azabenzanthrone; Hydroxylation; Hydrazine hydrate; Hydroxylamine hydrochloride; Sodium hydroxide;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and facile method of introducing 4-hydroxyl group into the aromatic ring of azabenzanthrone compounds was carried out by reacting azabenzanthrone compounds with hydrazine hydrate or hydroxylamine hydrochloride and sodium hydroxide in diethylene glycol(DEG) solvent.The mechanism of reaction may involve an amino intermediate and follow a hydroxyl substitution process.
引用
收藏
页码：41 / 44
页数：4
相关论文
共 50 条
  • [41] Immobilization of Enzymes on Cyclodextrin-Anchored Dehiscent Mesoporous TiO2 for Efficient Photoenzymatic Hydroxylation
    Jia, Feifei
    Liu, Yunting
    Deng, Xuewu
    Cao, Xue
    Zheng, Xiaobing
    Zhou, Liya
    Gao, Jing
    Jiang, Yanjun
    ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (06) : 7928 - 7938
  • [42] VxOy Supported on Hydrophobic Poly(Ionic Liquid)s as an Efficient Catalyst for Direct Hydroxylation of Benzene to Phenol
    Han, Hongling
    Jiang, Tao
    Wu, Tianbin
    Yang, Dexin
    Han, Buxing
    ChemCatChem, 2015, 7 (21) : 3526 - 3532
  • [43] An Electrochemical Method for Deborylative Hydroxylation of Arylboronic Acids under Metal-free Conditions
    Fu, Zhengjiang
    Yi, Xuezheng
    Fang, Ziqi
    Zhong, Tingting
    He, Dongdong
    Guo, Shengmei
    Cai, Hu
    CHEMISTRY-AN ASIAN JOURNAL, 2022, 17 (24)
  • [44] Copper phthalocyanine as an efficient and reusable heterogeneous catalyst for direct hydroxylation of benzene to phenol under mild conditions
    Farahmand, Shohreh
    Ghiaci, Mehran
    Razavizadeh, Jala. S.
    INORGANICA CHIMICA ACTA, 2019, 484 : 174 - 179
  • [45] Facile and controlled synthesis of FeCo nanoparticles via a hydrothermal method
    Chunju Xu
    Yujie Wang
    Huiyu Chen
    Dan Nie
    Yaqing Liu
    Journal of Materials Science: Materials in Electronics, 2014, 25 : 1965 - 1969
  • [46] An efficient synthesis of 4(5),11(12)-taxadiene derivatives and microbial mediated 20-hydroxylation of taxoids
    Hu, SH
    Sun, D
    Scott, AI
    TETRAHEDRON LETTERS, 2000, 41 (11) : 1703 - 1705
  • [47] An Efficient Synthesis of Phenol via CuI/8-Hydroxyquinoline-Catalyzed Hydroxylation of Aryl Halides and Potassium Hydroxide
    Maurer, Stefan
    Liu, Wei
    Zhang, Xiaojing
    Jiang, Yongwen
    Ma, Dawei
    SYNLETT, 2010, (06) : 976 - 978
  • [48] Mn(III)-Initiated Facile Oxygenation of Heterocyclic 1,3-Dicarbonyl Compounds
    Rahman, Md. Taifur
    Haque, Md. Aminul
    Igarashi, Hikaru
    Nishino, Hiroshi
    MOLECULES, 2011, 16 (11): : 9562 - 9581
  • [49] SIDE-CHAIN HYDROXYLATION OF AROMATIC-COMPOUNDS BY FUNGI .6. BIOTRANSFORMATION OF OLEFINS BY MORTIERELLA-ISABELLINA
    HOLLAND, HL
    DESTAFANO, D
    OZOG, J
    BIOCATALYSIS, 1994, 10 (1-4): : 65 - 76
  • [50] A dinuclear iron(II) complex bearing multidentate pyridinyl ligand: Synthesis, characterization and its catalysis on the hydroxylation of aromatic compounds
    Gu, Erxing
    Zhong, Wei
    Ma, Hongxia
    Xu, Beibei
    Wang, Hailong
    Liu, Xiaoming
    INORGANICA CHIMICA ACTA, 2016, 444 : 159 - 165
12345